Synthesis of ZnOPolypyrrole Nanoring Composite as High-Performance Anode Materials for Lithium Ion Batteries
Joint Authors
Bakenov, Zhumabay
Wang, Xin
Li, Haipeng
Yang, Shuang
Zhao, Yan
Tan, Taizhe
Source
Issue
Vol. 2019, Issue 2019 (31 Dec. 2019), pp.1-8, 8 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2019-03-03
Country of Publication
Egypt
No. of Pages
8
Main Subjects
Abstract EN
ZnO has attracted considerable attention as electrode material in lithium-ion battery (LIB) due to its theoretically high capacity.
However, poor electronic conductivity and huge volumetric changes during cycling limit its industrial applications.
In this work, polypyrrole nanorings (PNRs) were successfully prepared via the solution chemistry method using pyrrole (Py) as raw material, ammonium persulfate (APS) as oxidant, and cetyltrimethyl ammonium bromide (CTAB) as surfactant.
The ZnO/PNR composite was synthesized with zinc oxide nanoparticles absorbed on the surface of PPy nanorings through the one-pot in situ sol-gel method.
The composite shows a three-dimensional intertwined network structure where the size of polypyrrole nanorings ranges from 80 nm to 100 nm in diameter and the average size of uniformly distributed ZnO nanocrystals is 10.49 nm.
The unique three-dimensional conductive framework can provide good electronic contact between the ZnO particles and buffer the volume variation during the lithiation/delithiation processes.
As an electrode material for LIBs, the ZnO/PNR composite delivers a first cycle discharge capacity of 1658 mAh g-1 and a capacity retention of 50.7% over 150 cycles at 200 mA g-1, indicating high specific capacity and outstanding cycle stability.
American Psychological Association (APA)
Li, Haipeng& Yang, Shuang& Zhao, Yan& Tan, Taizhe& Wang, Xin& Bakenov, Zhumabay. 2019. Synthesis of ZnOPolypyrrole Nanoring Composite as High-Performance Anode Materials for Lithium Ion Batteries. Journal of Nanomaterials،Vol. 2019, no. 2019, pp.1-8.
https://search.emarefa.net/detail/BIM-1182332
Modern Language Association (MLA)
Li, Haipeng…[et al.]. Synthesis of ZnOPolypyrrole Nanoring Composite as High-Performance Anode Materials for Lithium Ion Batteries. Journal of Nanomaterials No. 2019 (2019), pp.1-8.
https://search.emarefa.net/detail/BIM-1182332
American Medical Association (AMA)
Li, Haipeng& Yang, Shuang& Zhao, Yan& Tan, Taizhe& Wang, Xin& Bakenov, Zhumabay. Synthesis of ZnOPolypyrrole Nanoring Composite as High-Performance Anode Materials for Lithium Ion Batteries. Journal of Nanomaterials. 2019. Vol. 2019, no. 2019, pp.1-8.
https://search.emarefa.net/detail/BIM-1182332
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1182332