Synthesis, Spectral Characterization, and Thermal and Cytotoxicity Studies of Cr(III), Ru(III), Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) Complexes of Schiff Base Derived from 5-Hydroxymethylfuran-2-carbaldehyde
Joint Authors
Alturiqi, Amani S.
Alaghaz, Abdel-Nasser M. A.
Ammar, Reda A.
Zayed, Mohamed E.
Source
Issue
Vol. 2018, Issue 2018 (31 Dec. 2018), pp.1-17, 17 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2018-05-09
Country of Publication
Egypt
No. of Pages
17
Main Subjects
Abstract EN
Coordination compounds of Cr(III), Ru(III), Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) ions were synthesized from the furan ligand [5-hydroxymethylfuran-2-yl-methyleneaminoquinolin-2-one] (H-MFMAQ) derived from the condensation of 5-hydroxymethylfuran-2-carbaldehyde and 1-aminoquinolin-2(1H)-one.
Elemental analytical data, IR, NMR (1H, 13C, and 15N), EPR, XRD, SEM, TEM, EDX, TGA, mass, molar conductance, magnetic moment, and UV-Visible spectra techniques were used to confirm the structure of the synthesized chelates.
According to the data obtained, the composition of the 1 : 1 metal ions : furan Schiff base ligand was found to be [M(MFMAQ)Cl2] (M = Cr(III) and Ru(III)) and [M(MFMAQ)Cl(H2O)]·nH2O in which (M = Mn(II); n=1, Co(II); n=0, Ni(II); n=2, Cu(II); n=0 and Zn(II); n=2.5).
The measurements of magnetic susceptibility, ligand field parameter, and reflectance spectra suggested an octahedral geometry for the complexes.
Central metals ions and furan Schiff base coordinated via O3 and N donor sites which was observed from IR spectra.
The cytotoxic activities of all inspected compounds were evaluated towards human breast (MCF-7) and lung cancer (A549) cell lines.
American Psychological Association (APA)
Alturiqi, Amani S.& Alaghaz, Abdel-Nasser M. A.& Ammar, Reda A.& Zayed, Mohamed E.. 2018. Synthesis, Spectral Characterization, and Thermal and Cytotoxicity Studies of Cr(III), Ru(III), Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) Complexes of Schiff Base Derived from 5-Hydroxymethylfuran-2-carbaldehyde. Journal of Chemistry،Vol. 2018, no. 2018, pp.1-17.
https://search.emarefa.net/detail/BIM-1182454
Modern Language Association (MLA)
Alturiqi, Amani S.…[et al.]. Synthesis, Spectral Characterization, and Thermal and Cytotoxicity Studies of Cr(III), Ru(III), Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) Complexes of Schiff Base Derived from 5-Hydroxymethylfuran-2-carbaldehyde. Journal of Chemistry No. 2018 (2018), pp.1-17.
https://search.emarefa.net/detail/BIM-1182454
American Medical Association (AMA)
Alturiqi, Amani S.& Alaghaz, Abdel-Nasser M. A.& Ammar, Reda A.& Zayed, Mohamed E.. Synthesis, Spectral Characterization, and Thermal and Cytotoxicity Studies of Cr(III), Ru(III), Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) Complexes of Schiff Base Derived from 5-Hydroxymethylfuran-2-carbaldehyde. Journal of Chemistry. 2018. Vol. 2018, no. 2018, pp.1-17.
https://search.emarefa.net/detail/BIM-1182454
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1182454