Pd Nanoparticles Stabilized by Hypercrosslinked Polystyrene Catalyze Selective Triple C-C Bond Hydrogenation and Suzuki Cross-Coupling
Joint Authors
Sulman, Esther M.
Nikoshvili, Linda Zh.
Nemygina, Nadezhda A.
Khudyakova, Tatiana E.
Tiamina, Irina Yu.
Bykov, Alexey V.
Stein, Barry D.
Kiwi-Minsker, Lioubov
Source
Issue
Vol. 2019, Issue 2019 (31 Dec. 2019), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2019-01-13
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
This paper describes the synthesis of Pd-containing catalysts based on nonfunctionalized hypercrosslinked polystyrene via impregnation with Pd acetate.
Developed Pd nanoparticulate catalyst allowed achieving conversion of aryl halide up to 90% in Suzuki cross-coupling reaction under mild conditions and at the absence of phase-transfer agents.
During the selective hydrogenation of triple C-C bond of 2-methyl-3-butyn-2-ol, up to 96% selectivity with respect to corresponding olefinic alcohol was found at 95% conversion.
The influences of the procedure of catalyst synthesis like precursor decomposition and reductive activation method on Pd nanoparticle formation are discussed.
American Psychological Association (APA)
Nikoshvili, Linda Zh.& Nemygina, Nadezhda A.& Khudyakova, Tatiana E.& Tiamina, Irina Yu.& Bykov, Alexey V.& Stein, Barry D.…[et al.]. 2019. Pd Nanoparticles Stabilized by Hypercrosslinked Polystyrene Catalyze Selective Triple C-C Bond Hydrogenation and Suzuki Cross-Coupling. Journal of Nanomaterials،Vol. 2019, no. 2019, pp.1-7.
https://search.emarefa.net/detail/BIM-1182711
Modern Language Association (MLA)
Nikoshvili, Linda Zh.…[et al.]. Pd Nanoparticles Stabilized by Hypercrosslinked Polystyrene Catalyze Selective Triple C-C Bond Hydrogenation and Suzuki Cross-Coupling. Journal of Nanomaterials No. 2019 (2019), pp.1-7.
https://search.emarefa.net/detail/BIM-1182711
American Medical Association (AMA)
Nikoshvili, Linda Zh.& Nemygina, Nadezhda A.& Khudyakova, Tatiana E.& Tiamina, Irina Yu.& Bykov, Alexey V.& Stein, Barry D.…[et al.]. Pd Nanoparticles Stabilized by Hypercrosslinked Polystyrene Catalyze Selective Triple C-C Bond Hydrogenation and Suzuki Cross-Coupling. Journal of Nanomaterials. 2019. Vol. 2019, no. 2019, pp.1-7.
https://search.emarefa.net/detail/BIM-1182711
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1182711