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Effect of Soil Solution pH during the Tetracycline Intercalation on the Structural Properties of a Dioctahedral Smectite: Microstructural Analysis
Author
Source
Issue
Vol. 2019, Issue 2019 (31 Dec. 2019), pp.1-17, 17 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2019-09-12
Country of Publication
Egypt
No. of Pages
17
Main Subjects
Abstract EN
The aim of this work is to quantitatively characterize the structural response to a chemical disruption of saturated montmorillonite crystallites by organic molecules (tetracycline (TC)), derived from pharmaceutical waste.
The chemical disturbance is performed by varying the surrounding soil solution pH.
To show the effect of this chemical perturbation on the interlamellar space (IS) configuration and the hydration properties, an “in situ” XRD analysis, based on the modeling of the 00l reflections, is carried out.
The “in situ” XRD analysis is performed by varying the relative humidity conditions (%RH).
FTIR SEM and BET- (Brunauer-Emmett-Teller-) BJH (Barrett-Joyner-Halenda) analyses are used as complementary techniques to confirm the structural changes accompanying the intercalation process.
Results showed a dependence between solution acid character and the TC adsorption mechanism.
From pH values close to 7, the deprotonation of the TC molecule within IS is accelerated by an increasing %RH rate.
IR spectroscopy shows that the structure is preserved versus pH value and only a shift of the water deformation bands ascribed to interlamellar water molecule abundance and TC conformation is observed.
The surface morphology studied by SEM shows the increase in the surface porosity by increasing the pH value.
BET-specific surface area and BJH pore size distribution (PSD) analyses confirm the SEM observations.
American Psychological Association (APA)
Oueslati, W.. 2019. Effect of Soil Solution pH during the Tetracycline Intercalation on the Structural Properties of a Dioctahedral Smectite: Microstructural Analysis. Journal of Nanomaterials،Vol. 2019, no. 2019, pp.1-17.
https://search.emarefa.net/detail/BIM-1182945
Modern Language Association (MLA)
Oueslati, W.. Effect of Soil Solution pH during the Tetracycline Intercalation on the Structural Properties of a Dioctahedral Smectite: Microstructural Analysis. Journal of Nanomaterials No. 2019 (2019), pp.1-17.
https://search.emarefa.net/detail/BIM-1182945
American Medical Association (AMA)
Oueslati, W.. Effect of Soil Solution pH during the Tetracycline Intercalation on the Structural Properties of a Dioctahedral Smectite: Microstructural Analysis. Journal of Nanomaterials. 2019. Vol. 2019, no. 2019, pp.1-17.
https://search.emarefa.net/detail/BIM-1182945
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1182945