PolyethyleneGraphene Nanoplatelet Nanocomposite-Based Insulating Materials for Effective Reduction of Space Charge Accumulation in High-Voltage Direct-Current Cables

Abstract EN

We have demonstrated a straightforward hydrophobic surface modification of graphene nanoplatelets (GNPs) through a defect-healing process to fabricate well-dispersed insulating low-density polyethylene (LDPE)/GNP nanocomposites and have confirmed their effective suppression of space charge accumulation.

Without any organic modifiers, GNPs containing oxygen-based functional groups at the edges were successfully reduced at optimal high-temperature defect-healing condition and modified to have hydrophobic surface properties similar to those of the LDPE matrix.

The degree of dispersion and the reproducibility of the mechanically melt-mixed LDPE/GNP nanocomposites were immediately analyzed by thickness-normalized optical absorption measurement.

In the LDPE matrix, below the percolation threshold concentration, well-dispersed GNP fillers effectively acted as trapping sites under high electric fields, resulting in the successful suppression of packet-like space charge accumulation (field enhancement factor=1.04 @ 0.1 wt% LDPE/GNP nanocomposite).