Fabrication of Bifunctional TiO2POM Microspheres Using a Layer-by-Layer Method and Photocatalytic Activity for Methyl Orange Degradation
Joint Authors
Niu, Ping
Wang, Dunqing
Wang, Aili
Liang, Yuhua
Wang, Xinfang
Source
Issue
Vol. 2018, Issue 2018 (31 Dec. 2018), pp.1-8, 8 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2018-06-07
Country of Publication
Egypt
No. of Pages
8
Main Subjects
Abstract EN
Bifunctional films of Keggin-type polyoxometalates H3PW12O40 (PW12), H4SiW12O40 (SiW12), H3PMo12O40 (PMo12), and TiO2 were successfully built on Fe3O4@SiO2 microspheres using a layer-by-layer method.
The characterization by field emission scan electronic microscopy (FESEM) and energy dispersive X-ray spectroscopy (EDX) shows that TiO2 nanoparticles and polyoxometalate (POM) anions are successfully assembled.
The photodegradation of methyl orange (MO) was used to test the photocatalytic efficiency of magnetic catalysts under UV irradiation.
For MO decomposition, multilayer films that combine PW12 and SiW12 with TiO2 show high efficiency, which can be attributed to the synergistic effect between POMs and TiO2.
The degradation of the model contaminant was also systematically checked under different conditions such as bilayer number deposited on magnetic microspheres, catalyst concentration, inorganic oxidants, and salts.
The oxidation process of MO follows an apparent first-order reaction.
Furthermore, the composite catalysts deposited on Fe3O4@SiO2 magnetic microspheres can be conveniently, quickly, and efficiently separated by an external magnet from a solution.
American Psychological Association (APA)
Niu, Ping& Wang, Dunqing& Wang, Aili& Liang, Yuhua& Wang, Xinfang. 2018. Fabrication of Bifunctional TiO2POM Microspheres Using a Layer-by-Layer Method and Photocatalytic Activity for Methyl Orange Degradation. Journal of Nanomaterials،Vol. 2018, no. 2018, pp.1-8.
https://search.emarefa.net/detail/BIM-1194105
Modern Language Association (MLA)
Niu, Ping…[et al.]. Fabrication of Bifunctional TiO2POM Microspheres Using a Layer-by-Layer Method and Photocatalytic Activity for Methyl Orange Degradation. Journal of Nanomaterials No. 2018 (2018), pp.1-8.
https://search.emarefa.net/detail/BIM-1194105
American Medical Association (AMA)
Niu, Ping& Wang, Dunqing& Wang, Aili& Liang, Yuhua& Wang, Xinfang. Fabrication of Bifunctional TiO2POM Microspheres Using a Layer-by-Layer Method and Photocatalytic Activity for Methyl Orange Degradation. Journal of Nanomaterials. 2018. Vol. 2018, no. 2018, pp.1-8.
https://search.emarefa.net/detail/BIM-1194105
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1194105