Structural and Kinetic Hydrogen Sorption Properties of Zr0.8Ti0.2Co Alloy Prepared by Ball Milling
Joint Authors
He, Hui
Kou, Huaqin
Luo, Wenhua
Tang, Tao
Huang, Zhiyong
Sang, Ge
Zhang, Guanghui
Ba, Jingwen
Liu, Meng
Source
Issue
Vol. 2018, Issue 2018 (31 Dec. 2018), pp.1-13, 13 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2018-03-12
Country of Publication
Egypt
No. of Pages
13
Main Subjects
Information Technology and Computer Science
Abstract EN
The effects of ball milling on the hydrogen sorption kinetics and microstructure of Zr0.8Ti0.2Co have been systematically studied.
Kinetic measurements show that the hydrogenation rate and amount of Zr0.8Ti0.2Co decrease with increasing the ball milling time.
However, the dehydrogenation rate accelerates as the ball milling time increases.
Meanwhile, the disproportionation of Zr0.8Ti0.2Co speeds up after ball milling and the disproportionation kinetics is clearly inclined to be linear with time at 500°C.
It is found from X-ray powder diffraction (XRD) results that the lattice parameter of Zr0.8Ti0.2Co gradually decreases from 3.164 Å to 3.153 Å when the ball milling time extends from 0 h to 8 h, which is mainly responsible for the hydrogen absorption/desorption behaviors.
In addition, scanning electron microscope (SEM) images demonstrate that the morphology of Zr0.8Ti0.2Co has obviously changed after ball milling, which is closely related to the hydrogen absorption kinetics.
Besides, high-resolution transmission electron microscopy (HRTEM) images show that a large number of disordered microstructures including amorphous regions and defects exist after ball milling, which also play an important role in hydrogen sorption performances.
This work will provide some insights into the principles of how to further improve the hydrogen sorption kinetics and disproportionation property of Zr0.8Ti0.2Co.
American Psychological Association (APA)
He, Hui& Kou, Huaqin& Luo, Wenhua& Tang, Tao& Huang, Zhiyong& Sang, Ge…[et al.]. 2018. Structural and Kinetic Hydrogen Sorption Properties of Zr0.8Ti0.2Co Alloy Prepared by Ball Milling. Scanning،Vol. 2018, no. 2018, pp.1-13.
https://search.emarefa.net/detail/BIM-1212929
Modern Language Association (MLA)
He, Hui…[et al.]. Structural and Kinetic Hydrogen Sorption Properties of Zr0.8Ti0.2Co Alloy Prepared by Ball Milling. Scanning No. 2018 (2018), pp.1-13.
https://search.emarefa.net/detail/BIM-1212929
American Medical Association (AMA)
He, Hui& Kou, Huaqin& Luo, Wenhua& Tang, Tao& Huang, Zhiyong& Sang, Ge…[et al.]. Structural and Kinetic Hydrogen Sorption Properties of Zr0.8Ti0.2Co Alloy Prepared by Ball Milling. Scanning. 2018. Vol. 2018, no. 2018, pp.1-13.
https://search.emarefa.net/detail/BIM-1212929
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1212929