Synthesis, spectral and antibacterial studies of some transition metal complexes with Schiff base derived from Thiosemicarbazide and Phthalaldyde
Other Title(s)
تحضير و دراسة طيفية و دراسة ضد البكتيريا لبعض متراكبات العناصر الانتقالية مع قاعدة شيف المشتقة من Thiosemicarbazide and Phthalaldyde
Joint Authors
Khalifah, Khalifah Misbah
Mubarak, Iman Ibrahim
al-Khayali, Yunus A.
Hamil, Abd al-Salam Matuq Ali
Source
Journal of Pure and Applied Sciences
Issue
Vol. 19, Issue 2 (30 Jun. 2020), pp.135-140, 6 p.
Publisher
Publication Date
2020-06-30
Country of Publication
Libya
No. of Pages
6
Main Subjects
Abstract EN
Three transition metal Cr(III), Ni(II) and Cu(II) complexes of the Schiff base N,N՛-((1Z,1՛E)1,2-phenylenebis(methanelylidene)-bis(hydrazinecarbothioamide) have been synthesised and investigated using several techniques: physical characteristics, UV-Vis, mass spectra, molar conductivity, magnetic moment measurements, micro-analytical data (CHNS), 1HNMR and IR.
The micro-analytical data indicate the formation of a 1:1[M:L] ratio.
The molar conductance measurement showed that the [NiL(Cl)2] complex has non-electrolytic nature.
The molar conductance measurements of the complexes [Cr(H2L)(Cl)2 and [Cu(H2L)(H2O)2]Cl2 were electrolyte in nature and [Ni(H2O)Cl2] was non-electrolyte in nature.
The infrared spectral data displayed the main coordination sites of N,N՛-((1Z,1՛E)1,2-phenylenebis (methane lylidene)-bis(hydrazinecarbothioamide) towards Cr(III), Ni(II) and Cu(II) ions.
The electronic spectral results exhibited the presence of the electronic transitions in the free Schiff base and its complexes, the data suggested that the Cr(III), Ni(II) and Cu(II) complexes have an octahedral geometrical structure.
American Psychological Association (APA)
Khalifah, Khalifah Misbah& Hamil, Abd al-Salam Matuq Ali& Mubarak, Iman Ibrahim& al-Khayali, Yunus A.. 2020. Synthesis, spectral and antibacterial studies of some transition metal complexes with Schiff base derived from Thiosemicarbazide and Phthalaldyde. Journal of Pure and Applied Sciences،Vol. 19, no. 2, pp.135-140.
https://search.emarefa.net/detail/BIM-1284991
Modern Language Association (MLA)
Khalifah, Khalifah Misbah…[et al.]. Synthesis, spectral and antibacterial studies of some transition metal complexes with Schiff base derived from Thiosemicarbazide and Phthalaldyde. Journal of Pure and Applied Sciences Vol. 19, no. 2 (2020), pp.135-140.
https://search.emarefa.net/detail/BIM-1284991
American Medical Association (AMA)
Khalifah, Khalifah Misbah& Hamil, Abd al-Salam Matuq Ali& Mubarak, Iman Ibrahim& al-Khayali, Yunus A.. Synthesis, spectral and antibacterial studies of some transition metal complexes with Schiff base derived from Thiosemicarbazide and Phthalaldyde. Journal of Pure and Applied Sciences. 2020. Vol. 19, no. 2, pp.135-140.
https://search.emarefa.net/detail/BIM-1284991
Data Type
Journal Articles
Language
English
Notes
Record ID
BIM-1284991