Synthesis, spectral and antibacterial studies of some transition metal complexes with Schiff base derived from Thiosemicarbazide and Phthalaldyde

Other Title(s)

تحضير و دراسة طيفية و دراسة ضد البكتيريا لبعض متراكبات العناصر الانتقالية مع قاعدة شيف المشتقة من Thiosemicarbazide and Phthalaldyde

Joint Authors

Khalifah, Khalifah Misbah
Mubarak, Iman Ibrahim
al-Khayali, Yunus A.
Hamil, Abd al-Salam Matuq Ali

Source

Journal of Pure and Applied Sciences

Issue

Vol. 19, Issue 2 (30 Jun. 2020), pp.135-140, 6 p.

Publisher

Sabha University

Publication Date

2020-06-30

Country of Publication

Libya

No. of Pages

6

Main Subjects

Chemistry
Botany

Abstract EN

Three transition metal Cr(III), Ni(II) and Cu(II) complexes of the Schiff base N,N՛-((1Z,1՛E)1,2-phenylenebis(methanelylidene)-bis(hydrazinecarbothioamide) have been synthesised and investigated using several techniques: physical characteristics, UV-Vis, mass spectra, molar conductivity, magnetic moment measurements, micro-analytical data (CHNS), 1HNMR and IR.

The micro-analytical data indicate the formation of a 1:1[M:L] ratio.

The molar conductance measurement showed that the [NiL(Cl)2] complex has non-electrolytic nature.

The molar conductance measurements of the complexes [Cr(H2L)(Cl)2 and [Cu(H2L)(H2O)2]Cl2 were electrolyte in nature and [Ni(H2O)Cl2] was non-electrolyte in nature.

The infrared spectral data displayed the main coordination sites of N,N՛-((1Z,1՛E)1,2-phenylenebis (methane lylidene)-bis(hydrazinecarbothioamide) towards Cr(III), Ni(II) and Cu(II) ions.

The electronic spectral results exhibited the presence of the electronic transitions in the free Schiff base and its complexes, the data suggested that the Cr(III), Ni(II) and Cu(II) complexes have an octahedral geometrical structure.

American Psychological Association (APA)

Khalifah, Khalifah Misbah& Hamil, Abd al-Salam Matuq Ali& Mubarak, Iman Ibrahim& al-Khayali, Yunus A.. 2020. Synthesis, spectral and antibacterial studies of some transition metal complexes with Schiff base derived from Thiosemicarbazide and Phthalaldyde. Journal of Pure and Applied Sciences،Vol. 19, no. 2, pp.135-140.
https://search.emarefa.net/detail/BIM-1284991

Modern Language Association (MLA)

Khalifah, Khalifah Misbah…[et al.]. Synthesis, spectral and antibacterial studies of some transition metal complexes with Schiff base derived from Thiosemicarbazide and Phthalaldyde. Journal of Pure and Applied Sciences Vol. 19, no. 2 (2020), pp.135-140.
https://search.emarefa.net/detail/BIM-1284991

American Medical Association (AMA)

Khalifah, Khalifah Misbah& Hamil, Abd al-Salam Matuq Ali& Mubarak, Iman Ibrahim& al-Khayali, Yunus A.. Synthesis, spectral and antibacterial studies of some transition metal complexes with Schiff base derived from Thiosemicarbazide and Phthalaldyde. Journal of Pure and Applied Sciences. 2020. Vol. 19, no. 2, pp.135-140.
https://search.emarefa.net/detail/BIM-1284991

Data Type

Journal Articles

Language

English

Notes

Record ID

BIM-1284991