Silver ion-quinalphos complexes: kinetics and NMR studies
Joint Authors
Isbata, Abd al-Hamid A.
Buncel, Erwin
Vanloon, Gary W.
Source
Issue
Vol. 2020, Issue 17 العلوم التطبيقية (30 Jun. 2020), pp.58-64, 7 p.
Publisher
Publication Date
2020-06-30
Country of Publication
Libya
No. of Pages
7
Main Subjects
Abstract EN
Kinetics Studies have been carried out for the interaction between quinalphos and Ag+ at pH 4.0, 7.0 and 10.0 and temperature 25oC.
Kinetics data show that Ag+ facilitated the hydrolysis of quinalphos, as the observed rate constants increased by adding silver ion.
The extent of catalysis was greatly dependent on pH, as Kobs was found to increase with increasing pH.
In the second part of this research, Nuclear Magnetic Resonance (NMR) is the used instrument to investigate Ag+ - quinalphos complexes.
1H and 31P NMR of quinlaphos (Q), 1H of 2-hydroxyquinoxaline (HQ), and 31P of O,O-diethyl phosphorothioic acid (PA) were recorded.
1H and 31P NMR results were consistent with the interpretation that binding between Ag+ and quinalphos occurs primarily through two positions S and N.
American Psychological Association (APA)
Isbata, Abd al-Hamid A.& Buncel, Erwin& Vanloon, Gary W.. 2020. Silver ion-quinalphos complexes: kinetics and NMR studies. Journal of Academic Research،Vol. 2020, no. 17 العلوم التطبيقية, pp.58-64.
https://search.emarefa.net/detail/BIM-1467095
Modern Language Association (MLA)
Isbata, Abd al-Hamid A.…[et al.]. Silver ion-quinalphos complexes: kinetics and NMR studies. Journal of Academic Research No. 17 Applied Science (Jun. 2020), pp.58-64.
https://search.emarefa.net/detail/BIM-1467095
American Medical Association (AMA)
Isbata, Abd al-Hamid A.& Buncel, Erwin& Vanloon, Gary W.. Silver ion-quinalphos complexes: kinetics and NMR studies. Journal of Academic Research. 2020. Vol. 2020, no. 17 العلوم التطبيقية, pp.58-64.
https://search.emarefa.net/detail/BIM-1467095
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references: p. 64
Record ID
BIM-1467095