Metal- and acid-free, TBN-mediated direct CAH nitration of arenes
Joint Authors
Xian, Mo
Xu, Guangqiang
Lv, Chengdong
Wang, Qinggang
Zhou, Li
Source
Journal of Saudi Chemical Society
Issue
Vol. 23, Issue 7 (30 Nov. 2019), pp.896-902, 7 p.
Publisher
Publication Date
2019-11-30
Country of Publication
Saudi Arabia
No. of Pages
7
Main Subjects
Engineering & Technology Sciences (Multidisciplinary)
Abstract EN
A metal-free, acid-free, direct and eco-friendly nitration methodology has been devel oped.
A tert-butyl nitrite efficiently promotes the direct C-H nitration of electron-rich arenes with good to excellent yields and regioselectivities.
The practical utility of this protocol has been demon strated in gram-scale nitration of crown ether and mono nitration of Sesamin.
A plausible free rad ical mechanism is proposed based on detailed experimental observations.
American Psychological Association (APA)
Xu, Guangqiang& Zhou, Li& Lv, Chengdong& Xian, Mo& Wang, Qinggang. 2019. Metal- and acid-free, TBN-mediated direct CAH nitration of arenes. Journal of Saudi Chemical Society،Vol. 23, no. 7, pp.896-902.
https://search.emarefa.net/detail/BIM-1493942
Modern Language Association (MLA)
Xu, Guangqiang…[et al.]. Metal- and acid-free, TBN-mediated direct CAH nitration of arenes. Journal of Saudi Chemical Society Vol. 23, no. 7 (Nov. 2019), pp.896-902.
https://search.emarefa.net/detail/BIM-1493942
American Medical Association (AMA)
Xu, Guangqiang& Zhou, Li& Lv, Chengdong& Xian, Mo& Wang, Qinggang. Metal- and acid-free, TBN-mediated direct CAH nitration of arenes. Journal of Saudi Chemical Society. 2019. Vol. 23, no. 7, pp.896-902.
https://search.emarefa.net/detail/BIM-1493942
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 9010902
Record ID
BIM-1493942
