Voltammatric studies of the redox reactions of some metal cyanide complexes at rotating disk electrode in dimethylformamide (DMF)‎

Abstract EN

Electroactivity, shown by the electroreduction of iron (III), manganese (III) and elctrooxiation of molybdenum (IV) alkyl cyanide complexes has been studied at rotating disk electrodes of gold, platinum and glassy carbon in dimethylformamide (DMF).

All the compounds except molybdenum complexes display defined voltammetric wave at all electrode.

the electrods kinetics parameter, conditional potentials, diffusion coefficients have been determined and the influence of the solvent and the electrode material has been elucidated.

comparison of the values obtained in the aqueous solution has been investigated.