Synthesis and study of dimethyl-2-(11-isoindolo [1,2-b] benzothiazolyl) but-2-ene-4-diate and related compounds
Joint Authors
Ali, Sami A.
Husayn, Salim H.
Yusuf, Walid Y.
Source
Issue
Vol. 2008, Issue 29 (31 Mar. 2008), pp.166-173, 8 p.
Publisher
University of Babylon College of Sciences
Publication Date
2008-03-31
Country of Publication
Iraq
No. of Pages
8
Main Subjects
Topics
Abstract AR
ثنائي مثيل (11-أيزواندول [1,2-b] بنزوثايزولال) بت-2-ين-4-دايوت (5) حضر من خلال تفاعل الأيزواندول [1,2-b] ثايزول (3) مع ثنائي مثيل أستيلين ثنائي الكاربوكسيل (4).
كذلك ناتج تفاعل الفثالديهايد مع مشتقات أمينية مختارة و 2-ثايوإيثانول بوجود ثنائي مثيل ثنائي الكاربوكسيل (4) تم الحصول عليه.
نظرية الكم و ميكانيكية الجزيئة طبقت لإثبات أن الأيزواندول أكثر تعرضا للهجوم الإلكتروفيلي للحصول على ناتج معوض مع أواصر مزدوجة متعاقبة متعددة و ليس ناتج ديلز-الدر.
تم تشخيص المركبات المحضرة بواسطة الطرق الفيزيائية و الكيميائية إضافة إلى الطرق الطيفية المتوافرة.
Abstract EN
The new ligand 2-[(6-nitro - 2 benzo thiazolyl) azo]-hydroquinon (6-NO2BTAHQ=LH2) was prepared by coupling reaction between (6-nitro-2- Benzothiazolyldiazonium) chloride with quinoa in alkaline alcoholic solution.
Six new chelate complexes of Zn (II), Cd (II), Hg (II), Ga (III), In (III) and Tl (III) have been synthesized.
These complexes were prepared after fixing the optimum conditions of pH and molar concentration by studying Uv-vis.
Spectra of the solutions that mixing the metal ions with the ligand solution in a wide ranges pH = 4.5-9.0 and molar concentration that obeyed Lambert-Beer's law.
The structures of the prepared complexes have been characterized by using the molar ratio method for the metal: ligand, which is (1:2), the ligand and its complexes were investigate by using element analysis, molar conductance measurement, stability constant (β ), Uv-vis., infrared spectra and mass spectrum of the ligand.
Atomic absorption, flame emission spectrophotometer was used to determine the prevents of metal ions in the prepared complexes.
American Psychological Association (APA)
Ali, Sami A.& Husayn, Salim H.& Yusuf, Walid Y.. 2008. Synthesis and study of dimethyl-2-(11-isoindolo [1,2-b] benzothiazolyl) but-2-ene-4-diate and related compounds. National Journal of Chemistry،Vol. 2008, no. 29, pp.166-173.
https://search.emarefa.net/detail/BIM-240650
Modern Language Association (MLA)
Ali, Sami A.…[et al.]. Synthesis and study of dimethyl-2-(11-isoindolo [1,2-b] benzothiazolyl) but-2-ene-4-diate and related compounds. National Journal of Chemistry No. 29 (2008), pp.166-173.
https://search.emarefa.net/detail/BIM-240650
American Medical Association (AMA)
Ali, Sami A.& Husayn, Salim H.& Yusuf, Walid Y.. Synthesis and study of dimethyl-2-(11-isoindolo [1,2-b] benzothiazolyl) but-2-ene-4-diate and related compounds. National Journal of Chemistry. 2008. Vol. 2008, no. 29, pp.166-173.
https://search.emarefa.net/detail/BIM-240650
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 173
Record ID
BIM-240650