New trinuclear complexes of Co(Ii),Ni(ii) ,Cu(Ii) and Zn(Ii) with thiolato triazole, dithiocarbamate indium (Iii) and their biological study
Joint Authors
Buttrus, Nabil Hadi
al-Umari, A. F.
Yasin, E.
Source
Issue
Vol. 2010, Issue 37 (31 Mar. 2010), pp.101-110, 10 p.
Publisher
University of Babylon College of Sciences
Publication Date
2010-03-31
Country of Publication
Iraq
No. of Pages
10
Main Subjects
Abstract AR
يتفاعل فلز الانديوم مع الليكاندات (C3H4N3S)2 (L1) و (L2) (C5H14N3S2)2 في التولوين لتعطي المركبات ذوات الصيغ [In(L1)3] و [In(L2)3] خلال تفاعل الأكسدة المضافة.
كذلك تم تحضير المعقدات ثلاثية النوى الجديدة ذوات الصيغ العامة [In(L1)3 (MCI2)2] و [In(L2)3(MCl2)2] (M=Co , Ni, Cu and Zn) خلال تفاعل الإضافة المباشرة مع مركبات الانديوم أعلاه.
تم تشخيص المركبات و المعقدات بواسطة أطياف تم تشخيص المركبات و المعقدات بواسطة أطياف الأشعة تحت الحمراء و فوق البنفسجية و التوصيلية الكهربائية و القياسات المغناطيسية.
كذلك تم تقدير المحتوى الفلزي بالطريقة الطيفية و كذلك تم دراسة الفعالية البايولوجية لبعض المركبات المحضرة.
بينت القياسات المغناطيسية و الطيف الالكتروني بان معقدات Ni, Co تمتلك بنية ثمانية السطوح و أما النحاس فتمتلك بنية رباعية السطوح و كذلك ثمانية السطوح.
Abstract EN
Indium metal react with (C3H4N3S)2 (L1) or (C5H14N3S2) 2 (L2) in refluxing toluene to give the compounds [In (L1) 3] and [In (L2) 3] through an oxidative addition reaction.
Trinuclear complexes of general formulas [In (L1) 3 (MCl2) 2] and [In (L2) 3 (MCl2) 2] were prepared by a direct reaction of MCl2.
6H2O, (M = Co, Ni) or CuCl2.
2H2O and ZnCl2.
XH2O with the above indium compounds.
The prepared compounds and complexes were characterized by IR and UV/Vis spectra, conductivity measurement, magnetic measurements, metal content were determined spectrophotometrically and their biological activity were also determined.The electronic spectra and magnetic measurements indicate that the Co and Ni complexes have square plan and octahedral geometry, while the Cu complexes show the presence of tetrahedral and octahedral geometry.
American Psychological Association (APA)
Buttrus, Nabil Hadi& al-Umari, A. F.& Yasin, E.. 2010. New trinuclear complexes of Co(Ii),Ni(ii) ,Cu(Ii) and Zn(Ii) with thiolato triazole, dithiocarbamate indium (Iii) and their biological study. National Journal of Chemistry،Vol. 2010, no. 37, pp.101-110.
https://search.emarefa.net/detail/BIM-240895
Modern Language Association (MLA)
Buttrus, Nabil Hadi…[et al.]. New trinuclear complexes of Co(Ii),Ni(ii) ,Cu(Ii) and Zn(Ii) with thiolato triazole, dithiocarbamate indium (Iii) and their biological study. National Journal of Chemistry No. 37 (2010), pp.101-110.
https://search.emarefa.net/detail/BIM-240895
American Medical Association (AMA)
Buttrus, Nabil Hadi& al-Umari, A. F.& Yasin, E.. New trinuclear complexes of Co(Ii),Ni(ii) ,Cu(Ii) and Zn(Ii) with thiolato triazole, dithiocarbamate indium (Iii) and their biological study. National Journal of Chemistry. 2010. Vol. 2010, no. 37, pp.101-110.
https://search.emarefa.net/detail/BIM-240895
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 110
Record ID
BIM-240895