Removal of Malachite green dye (MG)‎ from water by using residual tea leaves (RTL)‎ as adsorbent

Author

al-Karagoli, Bassim Muhammad H.

Source

National Journal of Chemistry

Issue

Vol. 2009, Issue 36 (31 Dec. 2009), pp.690-699, 10 p.

Publisher

University of Babylon College of Sciences

Publication Date

2009-12-31

Country of Publication

Iraq

No. of Pages

10

Main Subjects

Chemistry

Topics

Abstract AR

يعني هذا البحث في إزالة الملونات.

و قد تم في هذه الدراسة امتزاز صبغة المليخايت الخضراء (MG) على سطح ألياف الشاي و ذلك كدالة مع درجة الحرارة، و كمية الصبغة، و الدالة الحامضية.

كمية الامتزاز حددت باستخدام المطيافية المرئية، و من ثم تم مواءمة النتائج مع معادلات كل من لانكماير، و فرندلج، و ثوابت كلتا المعادلتين تم احتسابها من خلال الميل و نقطة التقاطع مع الإحداثيات المقابلة لكل حالة.

ايسوثرمات الامتزاز تم حسابها عند درجات حرارية مطلق مختلفة (318-298)، و وجد إن كمية الامتزاز تزداد مع زيادة درجات الحرارة ضمن هذا المدى.

كذلك تم حساب ايسوثرمات الامتزاز عند دوال حامضية مختلفة (7,5,3) و وجد أن كمية الامتزاز تقل مع زيادة الدالة الحامضية .

تم حساب الدوال الثرموديناميكية ∆G°، ∆H°، ∆S° و من خلالها تم دراسة سلوكية التركيب الكيميائي للمادة الممتزة، بينت النتائج أن عملية الامتزاز هي ماصة للحرارة.

Abstract EN

The present study is related to the removal of colorants.

Adsorption of Malachite green dye on residual tea leaves was studied as a function of temperature, amount of adsorbent and pH. A spectrophotometer technique was used for measuring the extent of adsorption.

The data were fitted with Langmuir and Freundlich, isotherm equations and their corresponding constants were calculated from the slopes and intercepts of their respective lines. The measured adsorption isotherms at the different temperatures 298 K, 308 K and 318 K were found that adsorption increase as the temperature increase within this range.

from the measured adsorption isotherms at different pHs 3, 5 and 7it was found that the adsorbed amount of MG dye increases with increased acidity. Thermodynamic parameters such as standard enthalpy change (ΔHo), standard Gibbs energy change (ΔGo), and standard entropy change (ΔSo) of adsorption were calculated, and were explained in the mean of the chemical structure of the adsorbate. Results are showed that the adsorption process is endothermic.

American Psychological Association (APA)

al-Karagoli, Bassim Muhammad H.. 2009. Removal of Malachite green dye (MG) from water by using residual tea leaves (RTL) as adsorbent. National Journal of Chemistry،Vol. 2009, no. 36, pp.690-699.
https://search.emarefa.net/detail/BIM-240997

Modern Language Association (MLA)

al-Karagoli, Bassim Muhammad H.. Removal of Malachite green dye (MG) from water by using residual tea leaves (RTL) as adsorbent. National Journal of Chemistry No. 36 (2009), pp.690-699.
https://search.emarefa.net/detail/BIM-240997

American Medical Association (AMA)

al-Karagoli, Bassim Muhammad H.. Removal of Malachite green dye (MG) from water by using residual tea leaves (RTL) as adsorbent. National Journal of Chemistry. 2009. Vol. 2009, no. 36, pp.690-699.
https://search.emarefa.net/detail/BIM-240997

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references : p. 699

Record ID

BIM-240997