Synthesis and spectroscopic characterization on the tri-iodide charge transfer complex resulted from the interaction between morpholine as donor and iodine c-acceptor

Abstract EN

Charge-transfer (CT) complex formed between morpholine (Morp) as donor with iodine (I2) as acceptor has been studied spectrophotometrically.

The synthesis and characterization of morpholine CT-complex of iodine, [(Morp) 2] I+ .

13- was described.

This complex is readily prepared from the reaction of Morp with I2 within CHC13 solvent.

IR spectra, UV-Vis techniques and elemental analyses (C, H and N), characterize the Morph charge-transfer complex.

Benesi-Hildebrand and its modification methods were applied to the determination of association constant (K), molar extinction coefficient (e).