Hydrogen-bonded phosphorous acids. synthesis and structure phenylphosphonate of imidazolium-containing salts of hydrogenphosphonate and phenylphosphonate
Joint Authors
Abu Salim, Qutaybah
Suwaydan, Kamal
Mallah, Iyad
Joshi, Rajendra
Steinmann, Manfred
Voelter, Wolfgang
Mubarak, Muhammad S.
Source
Issue
Vol. 6, Issue 2 (30 Jun. 2011), pp.113-121, 9 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2011-06-30
Country of Publication
Jordan
No. of Pages
9
Main Subjects
Topics
Abstract EN
Reaction of phosphorous acids with 1, 3-isopropyl-4,5-dimethylimidazol-2-laden (1) and 1, 3-dicyclohexyl-4,5-dimethylimidazol-2-laden (2) led to the formation of the hydrogen bonded salts, [H (4,5-Me) (iPr)2Im]H2PO3 (5) and [H (4,5-Me) (Cy) 2Im] PhPO3H (6) (Cy = Cyclohexyl) in high yields.
All were characterized by NMR, IR spectroscopy and single crystal X-ray diffraction.
Salts 5 and 6 crystallize in the monoclinic crystal system space groups.
The X-ray structures of 5 and 6 reveal unsymmetrical and symmetrical dimers of the phosphoryl anion groups linked to each other via intermolecular O-H•••O hydrogen bonds, respectively, and to the imidazolium cations through almost linear nonfunctional C-H•••O hydrogen bonds
American Psychological Association (APA)
Abu Salim, Qutaybah& Suwaydan, Kamal& Mallah, Iyad& Joshi, Rajendra& Mubarak, Muhammad S.& Steinmann, Manfred…[et al.]. 2011. Hydrogen-bonded phosphorous acids. synthesis and structure phenylphosphonate of imidazolium-containing salts of hydrogenphosphonate and phenylphosphonate. Jordan Journal of Chemistry،Vol. 6, no. 2, pp.113-121.
https://search.emarefa.net/detail/BIM-264407
Modern Language Association (MLA)
Abu Salim, Qutaybah…[et al.]. Hydrogen-bonded phosphorous acids. synthesis and structure phenylphosphonate of imidazolium-containing salts of hydrogenphosphonate and phenylphosphonate. Jordan Journal of Chemistry Vol. 6, no. 2 (Jun. 2011), pp.113-121.
https://search.emarefa.net/detail/BIM-264407
American Medical Association (AMA)
Abu Salim, Qutaybah& Suwaydan, Kamal& Mallah, Iyad& Joshi, Rajendra& Mubarak, Muhammad S.& Steinmann, Manfred…[et al.]. Hydrogen-bonded phosphorous acids. synthesis and structure phenylphosphonate of imidazolium-containing salts of hydrogenphosphonate and phenylphosphonate. Jordan Journal of Chemistry. 2011. Vol. 6, no. 2, pp.113-121.
https://search.emarefa.net/detail/BIM-264407
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 120-121
Record ID
BIM-264407