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Non-covalent interactions involved in the crystal structure of proton-transfer compounds of Saccharinate anion and different cations
Author
Source
Issue
Vol. 5, Issue 2 (30 Jun. 2010), pp.149-155, 7 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2010-06-30
Country of Publication
Jordan
No. of Pages
7
Main Subjects
Topics
Abstract EN
Proton-transfer compounds 4 and 5 of saccharin and nitrogen-containing aromatic derivatives were synthesized through mixing equimolar amounts of starting materials in ethanol.
The self-assembly of 4 and 5 was investigated and illustrated in terms of crystal engineering and supramolecular chemistry.
Both compounds contain cationic and anionic fragments interacting through hydrogen bonding patterns to produce ionic supramolecular heterosynthon.
Compound4 is monoclinic, space group P2(1) /c with unit cell dimensions a = 7.1068(4) Å, b = 13.4537(7) Å, c = 12.1912(7) Å, α = 90o, β = 93.6880(10)o, γ = 90o; while Compound 5 is orthorhombic, space group Pbca with unit cell dimensions a = 13.8743(10) Å, b = 12.4348(9) Å, c = 14.4155(10) Å, α = 90˚, β = 90o, γ = 90˚.
American Psychological Association (APA)
al-Ghazzawi, Nawwash Mamduh. 2010. Non-covalent interactions involved in the crystal structure of proton-transfer compounds of Saccharinate anion and different cations. Jordan Journal of Chemistry،Vol. 5, no. 2, pp.149-155.
https://search.emarefa.net/detail/BIM-266300
Modern Language Association (MLA)
al-Ghazzawi, Nawwash Mamduh. Non-covalent interactions involved in the crystal structure of proton-transfer compounds of Saccharinate anion and different cations. Jordan Journal of Chemistry Vol. 5, no. 2 (Jun. 2010), pp.149-155.
https://search.emarefa.net/detail/BIM-266300
American Medical Association (AMA)
al-Ghazzawi, Nawwash Mamduh. Non-covalent interactions involved in the crystal structure of proton-transfer compounds of Saccharinate anion and different cations. Jordan Journal of Chemistry. 2010. Vol. 5, no. 2, pp.149-155.
https://search.emarefa.net/detail/BIM-266300
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 155
Record ID
BIM-266300