Synthesis and crystal structure of bis-[co(l)‎(NCS)‎(MEOh)‎], where(lh = 4-(salicylaldimine)‎ antipyrine)‎

Joint Authors

al-Duwayk, A. N.
Kreddan, Khalid M.
al-Hamruni, S. H.
Bin Husayn, Hind
Hitchcok, P. B.
Shabash, A. A.
al-Mahdawi, Ramadan M.

Source

Jordan Journal of Chemistry

Issue

Vol. 5, Issue 2 (30 Jun. 2010), pp.157-164, 8 p.

Publisher

Yarmouk University Deanship of Research and Graduate Studies

Publication Date

2010-06-30

Country of Publication

Jordan

No. of Pages

8

Main Subjects

Chemistry

Topics

Abstract EN

The title complex was isolated as red solid material from the reaction of Co (SCN)2 with 4-(Salicylaldimine) antipyrine in ethanol.

The molecular structure has been determined by elemental analysis, FTIR, UV-Vis and X-ray diffraction.

The crystallographic data are: monoclinic P21/n, a = 9.8335(3) Å, b = 18.8593(6) Å, c = 11.2921(4) Å, α = 90°, β = 102.880(2)˚, γ = 90°, V =2041.46(12) Å3 and Z = 2, R =0.045.

The dicobalt (II) complex is Centro symmetric dimer in which the Co(II) ions are six coordinate being bonded to three coordinating donor sites from the corresponding tridentate Schiff base ligand and the fourth one is relatively bonded by phenolic oxygen, the fifth and sixth donor sites comes from isothiocyanate and methanol.

American Psychological Association (APA)

al-Mahdawi, Ramadan M.& al-Duwayk, A. N.& Kreddan, Khalid M.& al-Hamruni, S. H.& Bin Husayn, Hind& Hitchcok, P. B.…[et al.]. 2010. Synthesis and crystal structure of bis-[co(l)(NCS)(MEOh)], where(lh = 4-(salicylaldimine) antipyrine). Jordan Journal of Chemistry،Vol. 5, no. 2, pp.157-164.
https://search.emarefa.net/detail/BIM-266303

Modern Language Association (MLA)

al-Mahdawi, Ramadan M.…[et al.]. Synthesis and crystal structure of bis-[co(l)(NCS)(MEOh)], where(lh = 4-(salicylaldimine) antipyrine). Jordan Journal of Chemistry Vol. 5, no. 2 (Jun. 2010), pp.157-164.
https://search.emarefa.net/detail/BIM-266303

American Medical Association (AMA)

al-Mahdawi, Ramadan M.& al-Duwayk, A. N.& Kreddan, Khalid M.& al-Hamruni, S. H.& Bin Husayn, Hind& Hitchcok, P. B.…[et al.]. Synthesis and crystal structure of bis-[co(l)(NCS)(MEOh)], where(lh = 4-(salicylaldimine) antipyrine). Jordan Journal of Chemistry. 2010. Vol. 5, no. 2, pp.157-164.
https://search.emarefa.net/detail/BIM-266303

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references : p. 164

Record ID

BIM-266303