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Synthesis and solid-state structure analyses of a thia-bridged diquinolinium acetate compound
Joint Authors
Bishop, Roger
al-Shahatit, Sulhi Faysal
al-Ghazzawi, Nawwash Mamduh
Source
Issue
Vol. 5, Issue 3 (30 Sep. 2010), pp.211-220, 10 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2010-09-30
Country of Publication
Jordan
No. of Pages
10
Main Subjects
Topics
Abstract EN
The proton-transfer compound of this-bridged dinitrodiphenyldiquinoline 4 with acetic acid was obtained through crystallization of compound 3 from acetic acid.
Solid-state structure of 4 was determined by single-crystal X-ray diffraction.
Compound 4 was ionic, with proton transfer occurring from one acetic acid hydroxyl group to the aromatic nitrogen of one of the pyridine moiety leaving the other one unprotonated.
The versatile supramolecular self-assembly of 4 was carefully investigated and presented in term of crystal engineering and host-guest chemistry, interesting synthase including different motifs of hydrogen bonding, ion-pairing interactions were observed.
Compound 4 crystallized in the triclinic space group P-1.
The unit cell parameters were a = 8.9318(4) Å, b = 10.7353(5) Å, c = 17.3942(8) Å, with α = 87.0800(10)o, β = 87.6850(10)o, γ = 86.1640(10)o and with a final R value of 0.0848.
American Psychological Association (APA)
al-Ghazzawi, Nawwash Mamduh& al-Shahatit, Sulhi Faysal& Bishop, Roger. 2010. Synthesis and solid-state structure analyses of a thia-bridged diquinolinium acetate compound. Jordan Journal of Chemistry،Vol. 5, no. 3, pp.211-220.
https://search.emarefa.net/detail/BIM-266322
Modern Language Association (MLA)
al-Ghazzawi, Nawwash Mamduh…[et al.]. Synthesis and solid-state structure analyses of a thia-bridged diquinolinium acetate compound. Jordan Journal of Chemistry Vol. 5, no. 3 (Sep. 2010), pp.211-220.
https://search.emarefa.net/detail/BIM-266322
American Medical Association (AMA)
al-Ghazzawi, Nawwash Mamduh& al-Shahatit, Sulhi Faysal& Bishop, Roger. Synthesis and solid-state structure analyses of a thia-bridged diquinolinium acetate compound. Jordan Journal of Chemistry. 2010. Vol. 5, no. 3, pp.211-220.
https://search.emarefa.net/detail/BIM-266322
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 220
Record ID
BIM-266322