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Transimination ; a synthetic route to mixed legend Schiff base complexes
Joint Authors
al-Smadi, Fatimah
al-Rushaydat, Tariq
Hamdinah, Usamah
Source
Issue
Vol. 5, Issue 4 (31 Dec. 2010), pp.349-361, 13 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2010-12-31
Country of Publication
Jordan
No. of Pages
13
Main Subjects
Topics
Abstract EN
Copper and nickel Schiff base complexes have been prepared and reacted with aqueous ammonia and some amines.
A variety of Schiff bases have been chosen, two bi dentate Schiff bases; HSN and HNPY which are N-(2-hydroxy-1-naphthalidine)-3-aminopyridine and N-salicylidinenaphthylamine, respectively, three tridentate Schiff bases; HBN, HPN and HBS which are N-2-hydroxynaphthalidine-2-aminobenzoic acid, N-2-hydroxynaphtalidine-2-aminophenol and N-salicylidne-2-aminobenzoic acid, respectively, and one tetra dentate Schiff base which is N,N-(salicylidine)-4,5-dimethylphenylendiamine (H2Sal2Me2Ph).
The complexes derived from the bi dentate and the tetra dentate Schiff bases; [M (NPY) 2], [M (SN) 2] and [M (Sal2Me2Ph)] (M = Cu and Ni), undergo transamination reaction with a complete loss of the exchanged amine from the coordination sphere.
However, in case of the tridentate Schiff base complexes, M (PN), M (BN), M (BS), amine exchange took place and the eliminated amine gets bonded to the metal, which produced new type of mixed Schiff base complexes.
American Psychological Association (APA)
al-Smadi, Fatimah& al-Rushaydat, Tariq& Hamdinah, Usamah. 2010. Transimination ; a synthetic route to mixed legend Schiff base complexes. Jordan Journal of Chemistry،Vol. 5, no. 4, pp.349-361.
https://search.emarefa.net/detail/BIM-266355
Modern Language Association (MLA)
al-Smadi, Fatimah…[et al.]. Transimination ; a synthetic route to mixed legend Schiff base complexes. Jordan Journal of Chemistry Vol. 5, no. 4 (Dec. 2010), pp.349-361.
https://search.emarefa.net/detail/BIM-266355
American Medical Association (AMA)
al-Smadi, Fatimah& al-Rushaydat, Tariq& Hamdinah, Usamah. Transimination ; a synthetic route to mixed legend Schiff base complexes. Jordan Journal of Chemistry. 2010. Vol. 5, no. 4, pp.349-361.
https://search.emarefa.net/detail/BIM-266355
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 360-361
Record ID
BIM-266355