Crystal structure, and crystal supramolecularity of Bis (3,5- dimethylpyridinium) tetrahalocuprate (II) [halide = Cl or Br]
Joint Authors
al-Far, Ruhi
Ali, Basem F.
Haddad, Salim F.
Source
Issue
Vol. 4, Issue 2 (30 Jun. 2009), pp.131-141, 11 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2009-06-30
Country of Publication
Jordan
No. of Pages
11
Main Subjects
Topics
Abstract EN
The reaction of CuX2 (X = Cl or Br) with 3, 5-dimethylpyridine in aqueous acids (HX; X = Cl or Br) yields bis (3, 5-dimethylpyridinium) tetrachlorocuprate and tetrabromocuprate salts, 1 and2, respectively.
The crystal structures of the two compounds belong to the monoclinic space group Cs / 2.
In the crystal structure of both 1 and 2, the actions and anions are aggregated via classical hydrogen bonding of cationic pyridinium hydrogen's and X- of CuX42- and non-classical (π)C―H•••X intermolecular interactions into a layer supramolecular architecture parallel to c axis.
American Psychological Association (APA)
al-Far, Ruhi& Ali, Basem F.& Haddad, Salim F.. 2009. Crystal structure, and crystal supramolecularity of Bis (3,5- dimethylpyridinium) tetrahalocuprate (II) [halide = Cl or Br]. Jordan Journal of Chemistry،Vol. 4, no. 2, pp.131-141.
https://search.emarefa.net/detail/BIM-266471
Modern Language Association (MLA)
al-Far, Ruhi…[et al.]. Crystal structure, and crystal supramolecularity of Bis (3,5- dimethylpyridinium) tetrahalocuprate (II) [halide = Cl or Br]. Jordan Journal of Chemistry Vol. 4, no. 2 (Jun. 2009), pp.131-141.
https://search.emarefa.net/detail/BIM-266471
American Medical Association (AMA)
al-Far, Ruhi& Ali, Basem F.& Haddad, Salim F.. Crystal structure, and crystal supramolecularity of Bis (3,5- dimethylpyridinium) tetrahalocuprate (II) [halide = Cl or Br]. Jordan Journal of Chemistry. 2009. Vol. 4, no. 2, pp.131-141.
https://search.emarefa.net/detail/BIM-266471
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 140-141
Record ID
BIM-266471