Catalytic dimerization of propene with diiminophosphorane nickel(ii) complexes in the presence of phosphine additives
Joint Authors
Alt, Helmut G.
Schneider, Katharina J.
Funk, Edith
Source
Issue
Vol. 3, Issue 4 (31 Dec. 2008), pp.367-379, 13 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2008-12-31
Country of Publication
Jordan
No. of Pages
13
Main Subjects
Topics
Abstract EN
A series of 16 diiminophosphorane nickel (II) complexes was synthesized and used as catalyst precursors for dimerization reactions of propene.
The nickel complexes were activated with methylalumoxane (MAO) and various phosphine additives.
The influence of the ligand frameworks, the phosphine additives and the temperature was studied.
Activities of 1 200 [kg Oligomers / mol catalyst * h] and a selectivity of 76% for 2, 3-dimethylbutene were achieved.
American Psychological Association (APA)
Alt, Helmut G.& Schneider, Katharina J.& Funk, Edith. 2008. Catalytic dimerization of propene with diiminophosphorane nickel(ii) complexes in the presence of phosphine additives. Jordan Journal of Chemistry،Vol. 3, no. 4, pp.367-379.
https://search.emarefa.net/detail/BIM-275196
Modern Language Association (MLA)
Alt, Helmut G.…[et al.]. Catalytic dimerization of propene with diiminophosphorane nickel(ii) complexes in the presence of phosphine additives. Jordan Journal of Chemistry Vol. 3, no. 4 (Dec. 2008), pp.367-379.
https://search.emarefa.net/detail/BIM-275196
American Medical Association (AMA)
Alt, Helmut G.& Schneider, Katharina J.& Funk, Edith. Catalytic dimerization of propene with diiminophosphorane nickel(ii) complexes in the presence of phosphine additives. Jordan Journal of Chemistry. 2008. Vol. 3, no. 4, pp.367-379.
https://search.emarefa.net/detail/BIM-275196
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 379
Record ID
BIM-275196
