Preparation and physical investigation of complexes derived from 4-dimethylaminobenzaldehyde and 4-aminoantipyrine schiff base with NI (II), CU (II), RH (III), and PT (IV) ions
Joint Authors
al-Ujayli, M. M.
al-Farjani, R. M.
Maihub, A. A.
Source
Issue
Vol. 2, Issue 3 (31 Dec. 2007), pp.287-296, 10 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2007-12-31
Country of Publication
Jordan
No. of Pages
10
Main Subjects
Abstract EN
Four new Schiff base complexes derived from Ni (II), Cu (II), Rh (III), and Pt (IV) with4-dimethylaminobenzaldehyde and 4-aminoantipyrine were prepared and investigated using some elemental analysis such as molar conductivity measurements, thermo gravimetric analysis, magnetic moments, infrared, electronic and mass spectra.
The elemental analysis for C, H, and N showed the formation of 1:1 [M : L] complexes.
The molar conductivity measurements revealed that the complexes are nonelectrolyte in nature.
The thermo gravimetric analysis data exhibited the presence of coordinated and hydrated water molecules.
The magnetic moment results showed paramagnetic phenomena for nickel and copper complexes and diamagnetic phenomena for Rhodium and platinum complexes.
The infrared spectral data of the prepared complexes displayed the proper coordination sites of the present Schiff base towards the metal ions.
The electronic absorption spectral data of the prepared complexes confirmed the electronic transitions and the chemical structures.
The mass spectra of the free Schiff base and its complex with Rh (III) exhibited an interesting fragmentations.
American Psychological Association (APA)
al-Ujayli, M. M.& al-Farjani, R. M.& Maihub, A. A.. 2007. Preparation and physical investigation of complexes derived from 4-dimethylaminobenzaldehyde and 4-aminoantipyrine schiff base with NI (II), CU (II), RH (III), and PT (IV) ions. Jordan Journal of Chemistry،Vol. 2, no. 3, pp.287-296.
https://search.emarefa.net/detail/BIM-276874
Modern Language Association (MLA)
al-Ujayli, M. M.…[et al.]. Preparation and physical investigation of complexes derived from 4-dimethylaminobenzaldehyde and 4-aminoantipyrine schiff base with NI (II), CU (II), RH (III), and PT (IV) ions. Jordan Journal of Chemistry Vol. 2, no. 3 (Dec. 2007), pp.287-296.
https://search.emarefa.net/detail/BIM-276874
American Medical Association (AMA)
al-Ujayli, M. M.& al-Farjani, R. M.& Maihub, A. A.. Preparation and physical investigation of complexes derived from 4-dimethylaminobenzaldehyde and 4-aminoantipyrine schiff base with NI (II), CU (II), RH (III), and PT (IV) ions. Jordan Journal of Chemistry. 2007. Vol. 2, no. 3, pp.287-296.
https://search.emarefa.net/detail/BIM-276874
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 296
Record ID
BIM-276874