A novel Al3+-Selective potentiometric sensor based on 3, 4, 13, 14- tetraphenyl-2, 5, 12, 15-tetraazatricyclo[11, 0, 0611]cosa ; 1(16) , 2, 4, 7, 9, 6 (11), 12, 14, 17, 19-decaene in a PVC matrix and its application in analyzing biological fluids
Joint Authors
Chandra, Sulekh
Singh, Chandan Kumar
Agarwal, Himanshu
Source
Issue
Vol. 2, Issue 1 (30 Jun. 2007), pp.79-88, 10 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2007-06-30
Country of Publication
Jordan
No. of Pages
10
Main Subjects
Topics
Abstract EN
A novel PVC membrane electrode for Al3+ ion based on 3, 4, 13, 14-tetraphenyl-2, 5, 12, 15 tetraazatricyclo [11, 0, 0611] cosa ; 1(16), 2, 4, 7, 9, 6(11), 12, 14, 17, 19-decaene as a suitable ionophore was prepared.
The electrode exhibits a Nernstian response for Al3+ ion over a wide concentration range (4.0 x 10–8 to 1.0 x 10–1 M) with a slope of 19.58 ± 0.3 mV / decade.
The limit of detection is 2.0 x 10–8 M.
The electrode has a response time of 10 s and a useful working pH range of 3-11.
The proposed membrane sensor shows good discriminating abilities towards Al3 + ion with regard to several alkali, alkaline earth transition and heavy metal ions.
It was successfully used in the determination of aluminum ion in biological fluids and as an indicator electrode in the potentiometric titration of Al3+ ion with EDTA.
American Psychological Association (APA)
Chandra, Sulekh& Singh, Chandan Kumar& Agarwal, Himanshu. 2007. A novel Al3+-Selective potentiometric sensor based on 3, 4, 13, 14- tetraphenyl-2, 5, 12, 15-tetraazatricyclo[11, 0, 0611]cosa ; 1(16) , 2, 4, 7, 9, 6 (11), 12, 14, 17, 19-decaene in a PVC matrix and its application in analyzing biological fluids. Jordan Journal of Chemistry،Vol. 2, no. 1, pp.79-88.
https://search.emarefa.net/detail/BIM-276949
Modern Language Association (MLA)
Chandra, Sulekh…[et al.]. A novel Al3+-Selective potentiometric sensor based on 3, 4, 13, 14- tetraphenyl-2, 5, 12, 15-tetraazatricyclo[11, 0, 0611]cosa ; 1(16) , 2, 4, 7, 9, 6 (11), 12, 14, 17, 19-decaene in a PVC matrix and its application in analyzing biological fluids. Jordan Journal of Chemistry Vol. 2, no. 1 (Jun. 2007), pp.79-88.
https://search.emarefa.net/detail/BIM-276949
American Medical Association (AMA)
Chandra, Sulekh& Singh, Chandan Kumar& Agarwal, Himanshu. A novel Al3+-Selective potentiometric sensor based on 3, 4, 13, 14- tetraphenyl-2, 5, 12, 15-tetraazatricyclo[11, 0, 0611]cosa ; 1(16) , 2, 4, 7, 9, 6 (11), 12, 14, 17, 19-decaene in a PVC matrix and its application in analyzing biological fluids. Jordan Journal of Chemistry. 2007. Vol. 2, no. 1, pp.79-88.
https://search.emarefa.net/detail/BIM-276949
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 87-88
Record ID
BIM-276949