Synthesis, structural and biological studies of 3-(1, 3- benzothiazol-2-yl) - 4H- spiro[indole2,3-[1,3]thiazolidine]- 2,4(1H) dion with Cr (III), Mn (II), Co (II), Ni (II), Cu (II), and Zn (II) ions
Other Title(s)
تحضير و دراسة تركيبية و حيوية ل of 3-(1, 3- benzothiazol-2-yl) - 4H- spiro[indole2,3-[1,3]thiazolidine]- 2,4(1H) dion with Cr (III), Mn (II), Co (II), Ni (II), Cu (II), and Zn (II) ions
Joint Authors
al-Bayati, Sinan Midhat Muhammad
al-Azzawi, Sarab M. S.
al-Hasani, Rihab Abd al-Mahdi
Source
Engineering and Technology Journal
Issue
Vol. 29, Issue 15 (31 Dec. 2011), pp.3067-3078, 12 p.
Publisher
Publication Date
2011-12-31
Country of Publication
Iraq
No. of Pages
12
Main Subjects
Topics
Abstract AR
يتضمن هذا البحث تحضير المشتق الجديد 3-(1, 3-benzothiazol-2-yl) - L 4H- spiro [indole2, 3-[1, 3] thiazolidine] -2, / 4(1H) Dion من عمليية الغلق الحلقي لكل من (مشتق الأزوميثين) 3-(benzo[d] thiazol-2-ylimino) indolin-2- مع one [AB] α-mercaptoaceticacid جرى تشخيص (L) بطرائق تحليل طيف الأاشعة تحت الحمراء المعززة بتحولات فورير (FT.IR) و طيف الأشعة فوق البنفسجية المرئية و التحليل الدقيق للعناصر (C.H.N.S) ثم استخدام (L) كاليكد في نحضير معتقدات الأيونات الفلزية : الكروم (III)، المغنيز (II)، الكوبليت (II)، النيكل (II)، النحاس (II)، و الخارصين (II).
تم تشخيص المعتقدات الجديدة بواسطة طيف الأشعة تحت الحمراء (FT.IR) المعززة بتحويلات فورير و طيف الأشعة فوق البنفسجية المرئية و التحليل الدقيق للعناصر (C.H.N.S) و تقنية الامتصاص الذري اللهي للعناصر إضافة إلى القياسات الحساسية المغناطيسية و التوصيلية الكهربائية.
ثم تقويم الفاعلية المضادة للبكتيريا لليكاند (L) و معتقداته و اختير نوعان من البكتيريا (aerugionosa (Pseudonomousسالبة الصبغة (Bacillus subtitis) موجبة الصبغة لهذا الغرض.
Abstract EN
This paper describes the synthesis of a new derivative 3-(1, 3-benzothiazol-2-yl) / 4H- spiro[indole2,3-[1, 3] thiazolidine] -2, / 4 (1H) dion [L], which have been obtained from the cyclization of 3-(benzo [d] thiazol-2- ylimino) indolin -2-one[AB] through the addition of α-mercapto acetic acid.
The product [L] was characterized by (FT.IR) and (U.Vis) spectroscopy and in addition to element analysis (C.H.N.S.) A number of metal complexes were synthesized from the reaction of the ligand [L] with ions Cr (III), Mn (II), Co (II), Ni (II), Cu (II), and Zn (II).
The prepared complexes were isolated and characterized by using (FT.IR) and (U.Vis) spectroscopy in addition to element analysis (C.H.N.S.), flame atomic absorption technique, in addition to magnetic susceptibility and conductivity measurement.
The antibacterial activity of the ligand [L] and its complexes were studied against two selected micro-organisms (Pseudonomous aerugionosa) as gram negative and (Bacillus subtitis) as gram positive.
American Psychological Association (APA)
al-Hasani, Rihab Abd al-Mahdi& al-Bayati, Sinan Midhat Muhammad& al-Azzawi, Sarab M. S.. 2011. Synthesis, structural and biological studies of 3-(1, 3- benzothiazol-2-yl) - 4H- spiro[indole2,3-[1,3]thiazolidine]- 2,4(1H) dion with Cr (III), Mn (II), Co (II), Ni (II), Cu (II), and Zn (II) ions. Engineering and Technology Journal،Vol. 29, no. 15, pp.3067-3078.
https://search.emarefa.net/detail/BIM-289677
Modern Language Association (MLA)
al-Hasani, Rihab Abd al-Mahdi…[et al.]. Synthesis, structural and biological studies of 3-(1, 3- benzothiazol-2-yl) - 4H- spiro[indole2,3-[1,3]thiazolidine]- 2,4(1H) dion with Cr (III), Mn (II), Co (II), Ni (II), Cu (II), and Zn (II) ions. Engineering and Technology Journal Vol. 29, no. 15 (2011), pp.3067-3078.
https://search.emarefa.net/detail/BIM-289677
American Medical Association (AMA)
al-Hasani, Rihab Abd al-Mahdi& al-Bayati, Sinan Midhat Muhammad& al-Azzawi, Sarab M. S.. Synthesis, structural and biological studies of 3-(1, 3- benzothiazol-2-yl) - 4H- spiro[indole2,3-[1,3]thiazolidine]- 2,4(1H) dion with Cr (III), Mn (II), Co (II), Ni (II), Cu (II), and Zn (II) ions. Engineering and Technology Journal. 2011. Vol. 29, no. 15, pp.3067-3078.
https://search.emarefa.net/detail/BIM-289677
Data Type
Journal Articles
Language
English
Notes
Includes appendices : p. 3073-3078
Record ID
BIM-289677