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Porphyrin-based octanuclear Ti4M4 (M = Cu, Ag) transition metal complexes
Joint Authors
al-Anbar, Muhammad Ahmad
Lang, Heinrich
Tahir, D.
Source
Issue
Vol. 1, Issue 1 (31 Mar. 2006), pp.55-59, 5 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2006-03-31
Country of Publication
Jordan
No. of Pages
5
Main Subjects
Abstract EN
The synthesis of octanuclear Ti4M4 species (3a : M = Cu (I), 3b : M = Ag(I)) can be realised by the reaction of the organometallic π-tweezers {[Ti] (μ-σ, π-C ≡ CSiMe3)2} MX ([Ti] = (η5- C5H4SiMe3)2Ti ; 1a : MX = Cu(N ≡ CMe)ClO4, 1b : MX = AgFPF5) with 5, 10, 5, 20-tetra(4- pyridyl)porphyrin (2) in a 4 : 1 molar ratio.
In 3a and 3b four early-late [{[Ti](μ-σ, π-C ≡ CSiMe3)2}M]+ units are bridged by a (4-pyridyl)porphyrin core, whereby the pyridyl entities are datively bound to the group-11 metal atom M.
American Psychological Association (APA)
al-Anbar, Muhammad Ahmad& Tahir, D.& Lang, Heinrich. 2006. Porphyrin-based octanuclear Ti4M4 (M = Cu, Ag) transition metal complexes. Jordan Journal of Chemistry،Vol. 1, no. 1, pp.55-59.
https://search.emarefa.net/detail/BIM-290096
Modern Language Association (MLA)
al-Anbar, Muhammad Ahmad…[et al.]. Porphyrin-based octanuclear Ti4M4 (M = Cu, Ag) transition metal complexes. Jordan Journal of Chemistry Vol. 1, no. 1 (Mar. 2006), pp.55-59.
https://search.emarefa.net/detail/BIM-290096
American Medical Association (AMA)
al-Anbar, Muhammad Ahmad& Tahir, D.& Lang, Heinrich. Porphyrin-based octanuclear Ti4M4 (M = Cu, Ag) transition metal complexes. Jordan Journal of Chemistry. 2006. Vol. 1, no. 1, pp.55-59.
https://search.emarefa.net/detail/BIM-290096
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 59
Record ID
BIM-290096