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Synthesis and theoretical study of Cu (II) and V (IV) with 2-(2,3-dimethyl phenyl) amino benzoic acid ligands and 2-(2,5-dichloro phenyl) amino phenyl acetic acid
Author
Source
Issue
Vol. 24, Issue 1C (31 Aug. 2006), pp.48-67, 20 p.
Publisher
University of Basrah College of Science
Publication Date
2006-08-31
Country of Publication
Iraq
No. of Pages
20
Main Subjects
Topics
Abstract AR
تضمن هذا البحث تحضير و دراسة معقدات الفناديوم الرباعي النحاس الثنائي مع ليكاندين 2-(2.3 ثنائي مثيل فنيل) امينو حامض البنزويك 2-(2.5-ثنائي كلورو فينيل) امينو فنيل حامض الخليك.
شخصت المعقدات المحضرة باستخدام التوصيل المولاري و أطياف الأشعة تحت الحمراء و فوق البنفسجية.
دلت الدراسات المختلفة على عمل اليكاندين بشكل ثنائي السن و التناسق من خلال ذرة نتروجين و الأوكسجين.
كما استخدم بعض نظريات الميكانيك الجزيئي ZANDO/s, ZANDO/1 (hyper chem.
Program)MM+ لغرض حساب مختلف أنواع الطاقات و التي تعطي أكثر استقرارية متاحة للأشكال الهندسية المتوقعة لمعقدات المحضرة، و كذلك مقارنة أطياف الأشعة تحت الحمراء و فوق البنفسجية المحسوبة مع الأطياف المسجلة.
في حالة معقدات لنحاس اتضح أن للمعقدات التناسق الرباعي ذو بنية المربع المستوي.
كما لوحظ أيضا تناسق هرم مربع القاعدة في حالة الفناديوم الرباعي.
Abstract EN
New complexes of the ligands 2-(2, 3-dimethyl phenyl) amino benzoic acid and 2-(2, 5-dichloro phenyl) amino phenyl acetic acid with copper(II) and vanadyl (IV) ions have been prepared.
These complexes were characterized by infrared, U.
V-visible spectral data, molar conductivity and thermogravimetric analysis.
It was shown that the stoichemetry to be 1 : 2(metal to ligand), in which the ligands are acting as a bidentate ligands through the amino and carboxylate groups.
The molecular modeling of all complexes was performed using MM + molecular mechanics and ZINDO / 1, ZINDO / s semi-empirical methods.
The calculated IR, U.
V-visible data of the complexes have been compared with recorded spectrum.
The assignments of the most important vibrational modes are aided by the animation option of the HyperChem program.
The method used to simulate the geometry, ZINDO / 1, provide the best geometric copper Complex [I] and [III] described as distorted square planer, while oxovanadium complexes [II] and [IV] founded in the distorted square pyramidal.
The proposed mechanism of the interaction between the ligands and the Cu (II), VO (IV) cations was investigated.
American Psychological Association (APA)
Abbud, H. A.. 2006. Synthesis and theoretical study of Cu (II) and V (IV) with 2-(2,3-dimethyl phenyl) amino benzoic acid ligands and 2-(2,5-dichloro phenyl) amino phenyl acetic acid. Basrah Journal of Science،Vol. 24, no. 1C, pp.48-67.
https://search.emarefa.net/detail/BIM-290194
Modern Language Association (MLA)
Abbud, H. A.. Synthesis and theoretical study of Cu (II) and V (IV) with 2-(2,3-dimethyl phenyl) amino benzoic acid ligands and 2-(2,5-dichloro phenyl) amino phenyl acetic acid. Basrah Journal of Science Vol. 24, no. 1-C (2006), pp.48-67.
https://search.emarefa.net/detail/BIM-290194
American Medical Association (AMA)
Abbud, H. A.. Synthesis and theoretical study of Cu (II) and V (IV) with 2-(2,3-dimethyl phenyl) amino benzoic acid ligands and 2-(2,5-dichloro phenyl) amino phenyl acetic acid. Basrah Journal of Science. 2006. Vol. 24, no. 1C, pp.48-67.
https://search.emarefa.net/detail/BIM-290194
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 65-67
Record ID
BIM-290194