The effect of CNT doping on the hydrogenation behavior of Y5Si3 phases
Joint Authors
Husayn, Muayyad A.
Ali, Mahir Khalid
al-Isa, Salah Suud
Source
Iraqi National Journal of Chemistry
Issue
Vol. 2012, Issue 45 (31 Mar. 2012), pp.45-53, 9 p.
Publisher
University of Babylon College of Sciences
Publication Date
2012-03-31
Country of Publication
Iraq
No. of Pages
9
Main Subjects
Abstract AR
قورنت فعالية أنبوب الكاربون النانو cnt المعالج بالسبيكة 3si5y مع السبيكة 3si5y و تم التحقق منها‚ إن كلا السبيكتين حضرت من صهرهم بالقوس ودرست فعاليتهم مع الهيدروجين.
الطور الأحادي لسبيكة أنبوب الكاربون النانو cnt المعالج بالسبيكة 3si5y يمكن فقط تصنيعها بالإنصهار حتى تشكل السبيكة الجديدة من 3si5y مع أنبوب الكاربون النانو cnt.
إن عملية التنشيط تم تطويرها لاستمالة التفاعل مع السبيكة المعالجة باتجاه الهيدروجين ويتضمن تحولق في غاز الهيدروجين عند ضغط فوق 1,2 جو ودرجة حرارة أعلى من 435 سليزية اعتمادا على المحتوی من أنبوب الكاربون النانو ntc.
Abstract EN
The reactivity of the CNT-doped Y5Si3 compared to Y5Si3 phase system has been investigated.
Both alloys have been prepared by arc melting and their reactivity with hydrogen has been studied.
Single–phase CNT-doped Y5Si3 can only be made by melting preformed Y5Si3 with the CNT.
An activation process has been developed to induce reaction of the doped alloy with hydrogen.
It involves cycling in H2 gas pressures above 1.2 atm at temperature higher than 435oC depending on the CNT content.
Conditioned samples, will repeatedly (above 50 cycles) cycles 2.5 H (fu)-1 between room temperature and 500oC with 0.9 and 1.2 H (fu)-1 being desorbed and absorbed with fast kinetic within a very small temperature range.
This behavior is believed to arise from the polymorphic change between an α-form of the D88 structure and a supercell β-form.
An attempt to quantify the enhanced stability, compared to Y5Si3, is made by measuring reaction enthalpies using Van’t Hoff isopleths.
American Psychological Association (APA)
Husayn, Muayyad A.& Ali, Mahir Khalid& al-Isa, Salah Suud. 2012. The effect of CNT doping on the hydrogenation behavior of Y5Si3 phases. Iraqi National Journal of Chemistry،Vol. 2012, no. 45, pp.45-53.
https://search.emarefa.net/detail/BIM-303961
Modern Language Association (MLA)
Husayn, Muayyad A.…[et al.]. The effect of CNT doping on the hydrogenation behavior of Y5Si3 phases. Iraqi National Journal of Chemistry No. 45 (2012), pp.45-53.
https://search.emarefa.net/detail/BIM-303961
American Medical Association (AMA)
Husayn, Muayyad A.& Ali, Mahir Khalid& al-Isa, Salah Suud. The effect of CNT doping on the hydrogenation behavior of Y5Si3 phases. Iraqi National Journal of Chemistry. 2012. Vol. 2012, no. 45, pp.45-53.
https://search.emarefa.net/detail/BIM-303961
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 53
Record ID
BIM-303961