Synthesis and characterization of Co (II)‎, Ni (II)‎, Cu (II)‎ Zn (II)‎ and Cd (II)‎ mixed complexes of imidazol dithiocarbamate and 1, 10-phenanthroline

Abstract EN

Co (II) , Ni (II), Cu (II) Zn (II) and Cd (II) metal complexes of new imidazol dithiocarbamate of type [M (imid.dtc) 2] and mixed ligands complexes of the type [M (imid.dtc) 2.

phen] (phen = 1,10-phenanthroline) have been synthesized and characterized by elemental analysis (atomic absorption) infrared , electronic spectra , molar conductivity measurements and magnetic measurements .

It has been found that the imidazol dithiocarbamate behaves as a monodentate ligand in all complexes.

The suggest geometry of the four coordinate complexes , appear to be square planer , while octahedral are expected for mixed ligunds.