Self-assembly approach in the synthesis of supramolecular coordination polymers
Other Title(s)
طريقة التجمع الذاتي في تحضير المبلمرات ذات الأوزان الجزيئية العالية
Dissertant
Thesis advisor
University
Mutah University
Faculty
Faculty of Science
Department
Department of Chemistry
University Country
Jordan
Degree
Master
Degree Date
2009
English Abstract
-This thesis concerns with the synthesis of a series of novel supermolecule complexes and supramolecular polymers.
1D- and 2DSupermolecule Complexes of general formula [M(tba)2(H2O)2] {where M= Co(??): 3a, Zn(??): 3b, Fe(??): 3c, Mn(??): 3d and Ni(??): 3e; Htba: 3- benzoyl-1,1,1-trifluoro acetone (1a)} have been prepared by the selfassembly reaction.
These Supermolecule Complexes have been extended to construct 1D- and 2D- Supramolecular Coordination Polymers of the general formula [M(tba)2(bpy)]n {where M= Co(??): 5a, Zn(??): 5b, Fe(??): 5c, Mn(??): 5d and Ni(??): 5e; bpy = 4,4`-bipyridine (4)}.
The electronic and thermal properties of the prepared compounds are reported.
T he molecular structure of 3c has been discussed.
In which the coordination geometry of Fe(??) center ion is distorted octahedral.
The crystal data has obtained for 3c: C40H25F12FeO8, triclinic, P-1, a = 10.3560 (11)Å, b = 13.3161(11)Å, c = 14.6620(19)Å, ? = 108.536(10)º, ? = 99.002(10)º, ? = 92.705(8)º, Z = 2.
In addition, the molecular structure of 3c show three different types of the non-covalent intermolecular ??? interaction are present between the different phenyl ring of the coordinated ligand units and the non-coordinated ligand unit are found in the structure.
Main Subjects
No. of Pages
68
Table of Contents
Table of contents.
Abstract.
Chapter one : Introduction.
Chapter two : Experimental part.
Chapter three : Results and discussion.
Chapter four : Solid state structure and thermal studies.
References.
American Psychological Association (APA)
Dawud, Hanin Majid. (2009). Self-assembly approach in the synthesis of supramolecular coordination polymers. (Master's theses Theses and Dissertations Master). Mutah University, Jordan
https://search.emarefa.net/detail/BIM-304574
Modern Language Association (MLA)
Dawud, Hanin Majid. Self-assembly approach in the synthesis of supramolecular coordination polymers. (Master's theses Theses and Dissertations Master). Mutah University. (2009).
https://search.emarefa.net/detail/BIM-304574
American Medical Association (AMA)
Dawud, Hanin Majid. (2009). Self-assembly approach in the synthesis of supramolecular coordination polymers. (Master's theses Theses and Dissertations Master). Mutah University, Jordan
https://search.emarefa.net/detail/BIM-304574
Language
English
Data Type
Arab Theses
Record ID
BIM-304574
