Synthesis, characterization and supramolecularity of schiff base ligand transition metal complexes of schiff base ligands
Other Title(s)
تحضير و تشخيص و الجزيئية الفائقة لمتصلات قواعد شيف و مركباتها مع بعض العناصر الانتقالية
Dissertant
Thesis advisor
University
Mutah University
Faculty
Faculty of Science
Department
Department of Chemistry
University Country
Jordan
Degree
Master
Degree Date
2009
English Abstract
This thesis is concerned with the preparation and characterization of Schiff base ligands derived from the condensation of 2, 6-diformylpyridine, 2- Pyridinecarboxaldehyde and salicylaldehyde with four different diamantes namely, 2, 6-diaminopyridine (dap), 1, 2-phenylendiamine (daPh), trans-1, 2- diaminocyclohexane (dach), and ethylenediamine (en).
The Schiff base ligands were characterized by elemental analysis, melting points, FTIR, UV-vis., 1H-NMR and 13C-NMR.
Also, the structure of the Schiff base, N, N`-(bis (pyridine-2-yl) formylidene) ethane-1,2-diamine (L5) has been characterized by single-crystal X-ray diffraction.
The non-covalent supramolecular chemistry involved in the crystal structure of this ligand has been carefully investigated The Schiff base ligands are reacted with some transition metal ions using direct reaction or a template method.
The metal ions used are Pd (II) Pt (II), Pd (IV), and Pt (IV).
The formula obtained for the complexes are : PdC20H16N2O2Cl2, PdC20H15N2O2.BF4, PdC20H16N2O2Br2, PdC20H22N2O2Cl2, PdC20H22N2O2Br2, PdC20H20N2O2.2H2O, PdC18H20N4Cl2, Pd2C18H20N4Br4.H2O, Pt2C18H20N4Cl4.1.5PhCN, PtC18H20N4Br2, PdC16H16N2O2Cl2, PdC16H16N2O2Br2, PdC16H16N2O2 (BF4)2, Pd2C14H14N4Cl4, Pd2C14H14N4Br4, PtC14H14N4Cl2, PtC14H14N4Br2, PdC19H15N3O2Br2.PhCN.H2O, Pd2C17H13N5Cl4.3CH3CN.2H2O, PdC17H13N5 (BF4) 2.CH3CN.3H2O, PtC17H13N5Cl2, PtC17H13N5Br2, PdC17H13N5Cl4.0.5H2O, PtC17H13N5Cl4.0.5H2O.
The isolated compounds are characterized on the basis of their melting points, elemental analyses, conductivity measurements, nuclear magnetic resonance, FTIR and electronic absorption spectra.
Main Subjects
No. of Pages
114
Table of Contents
Table of contents.
Abstract.
Abstract in Arabic.
Chapter one : Introduction.
Chapter two : Experimental.
Chapter three : Result and discussion.
References.
American Psychological Association (APA)
al-Butush, Wail Ibrahim. (2009). Synthesis, characterization and supramolecularity of schiff base ligand transition metal complexes of schiff base ligands. (Master's theses Theses and Dissertations Master). Mutah University, Jordan
https://search.emarefa.net/detail/BIM-304976
Modern Language Association (MLA)
al-Butush, Wail Ibrahim. Synthesis, characterization and supramolecularity of schiff base ligand transition metal complexes of schiff base ligands. (Master's theses Theses and Dissertations Master). Mutah University. (2009).
https://search.emarefa.net/detail/BIM-304976
American Medical Association (AMA)
al-Butush, Wail Ibrahim. (2009). Synthesis, characterization and supramolecularity of schiff base ligand transition metal complexes of schiff base ligands. (Master's theses Theses and Dissertations Master). Mutah University, Jordan
https://search.emarefa.net/detail/BIM-304976
Language
English
Data Type
Arab Theses
Record ID
BIM-304976