Synthesis, characterization and supramolecularity of schiff base ligand transition metal complexes of schiff base ligands

Other Title(s)

تحضير و تشخيص و الجزيئية الفائقة لمتصلات قواعد شيف و مركباتها مع بعض العناصر الانتقالية

Dissertant

al-Butush, Wail Ibrahim

Thesis advisor

Qasir, Arab Khalil

University

Mutah University

Faculty

Faculty of Science

Department

Department of Chemistry

University Country

Jordan

Degree

Master

Degree Date

2009

English Abstract

This thesis is concerned with the preparation and characterization of Schiff base ligands derived from the condensation of 2, 6-diformylpyridine, 2- Pyridinecarboxaldehyde and salicylaldehyde with four different diamantes namely, 2, 6-diaminopyridine (dap), 1, 2-phenylendiamine (daPh), trans-1, 2- diaminocyclohexane (dach), and ethylenediamine (en).

The Schiff base ligands were characterized by elemental analysis, melting points, FTIR, UV-vis., 1H-NMR and 13C-NMR.

Also, the structure of the Schiff base, N, N`-(bis (pyridine-2-yl) formylidene) ethane-1,2-diamine (L5) has been characterized by single-crystal X-ray diffraction.

The non-covalent supramolecular chemistry involved in the crystal structure of this ligand has been carefully investigated The Schiff base ligands are reacted with some transition metal ions using direct reaction or a template method.

The metal ions used are Pd (II) Pt (II), Pd (IV), and Pt (IV).

The formula obtained for the complexes are : PdC20H16N2O2Cl2, PdC20H15N2O2.BF4, PdC20H16N2O2Br2, PdC20H22N2O2Cl2, PdC20H22N2O2Br2, PdC20H20N2O2.2H2O, PdC18H20N4Cl2, Pd2C18H20N4Br4.H2O, Pt2C18H20N4Cl4.1.5PhCN, PtC18H20N4Br2, PdC16H16N2O2Cl2, PdC16H16N2O2Br2, PdC16H16N2O2 (BF4)2, Pd2C14H14N4Cl4, Pd2C14H14N4Br4, PtC14H14N4Cl2, PtC14H14N4Br2, PdC19H15N3O2Br2.PhCN.H2O, Pd2C17H13N5Cl4.3CH3CN.2H2O, PdC17H13N5 (BF4) 2.CH3CN.3H2O, PtC17H13N5Cl2, PtC17H13N5Br2, PdC17H13N5Cl4.0.5H2O, PtC17H13N5Cl4.0.5H2O.

The isolated compounds are characterized on the basis of their melting points, elemental analyses, conductivity measurements, nuclear magnetic resonance, FTIR and electronic absorption spectra.

Main Subjects

Chemistry

No. of Pages

114

Table of Contents

Table of contents.

Abstract.

Abstract in Arabic.

Chapter one : Introduction.

Chapter two : Experimental.

Chapter three : Result and discussion.

References.

American Psychological Association (APA)

al-Butush, Wail Ibrahim. (2009). Synthesis, characterization and supramolecularity of schiff base ligand transition metal complexes of schiff base ligands. (Master's theses Theses and Dissertations Master). Mutah University, Jordan
https://search.emarefa.net/detail/BIM-304976

Modern Language Association (MLA)

al-Butush, Wail Ibrahim. Synthesis, characterization and supramolecularity of schiff base ligand transition metal complexes of schiff base ligands. (Master's theses Theses and Dissertations Master). Mutah University. (2009).
https://search.emarefa.net/detail/BIM-304976

American Medical Association (AMA)

al-Butush, Wail Ibrahim. (2009). Synthesis, characterization and supramolecularity of schiff base ligand transition metal complexes of schiff base ligands. (Master's theses Theses and Dissertations Master). Mutah University, Jordan
https://search.emarefa.net/detail/BIM-304976

Language

English

Data Type

Arab Theses

Record ID

BIM-304976