Study about complex formed between lanthanium (III) and organic reagent 2-[(4-bromo) phenyl azo]-4, 5-diphenyl imidazole
Joint Authors
al-Mutawalli, Nahlah Fatihe
Risan, Lamya Abd al-Latif
Abd al-Sahib, Maha
Source
Journal of Kufa for Chemical Science
Issue
Vol. 2012, Issue 5 (30 Jun. 2012), pp.89-97, 9 p.
Publisher
University of Kufa Faculty of Education for Women Department of Chemistry
Publication Date
2012-06-30
Country of Publication
Iraq
No. of Pages
9
Main Subjects
Topics
Abstract AR
تضمن البحث استخدام الكاشف 2-](4- بروموفنيل) ازو[-4, 5- ثنائي فنيل اميدازول (p-BrPAI) في تقدير كميات مايكروغرامية لأيون اللانثانيوم (III) بطريقة تحليلية طيفية سهلة و سريعة و حساسة.
حضر المعقد من تفاعل الكاشف العضوي مع أيون اللانثانيوم (III) عند أس هيدروجيني يساوي 10 و بنسبة 3:1 من الأيون المركزي إلى الكاشف العضوي عند الطول الموجي الأعظم 508 نانوميتر و معامل الامتصاص المولاري 6 × 104 L.mol-1.cm-1 و وجد أن التراكيز التي تطاوع قانون بيرلامبرت مساوية إلى (0.2_8) جزء بالمليون و تم تشخيص المعقد بواسطة تقنية F.T.I.R و UV-Vis.
كذلك تم تحديد الظروف الفضلى لتقدير هذا الأيون و تشمل الدالة الحامضية, حجم الكاشف, الفترة الزمنية و درجة الحرارة.
كما تم تحديد قيم R.S.D %, Re %, Erel % و هي 0.12, 98.7, -1.23 على التوالي و تم دراسة التداخلات المحتملة من تواجد بعض الأيونات الأخرى.
Abstract EN
The research include spectrophotometric method for determination Lanthanum (III) by use organic reagent -2 [(-4 bromo phenyl) azo] - 4, 5 diphenyl imidazole, pH (10) was favorable for complication reaction to with stoichiometry 1: 3 (metal : ligand) and maximum absorbance at lmax 508 nm and molar absorptivity 6 x 104 L.mol-1.cm-1.
Calibration curves of this complex were constructed.
Beers law was obeyed in the range (0.2 – 0.8) ppm, this complex identified by using F.T.I.R and UV-Vis Techniques, best conditions for the determination of this ion were employed, such as volume of reagent solution, period of time, temperature degree.
The precision and accuracy of the analytical procedure showed that (Erel, Re , R.S.D ) % were found to be (-1.23, 98.7, 0.12 ) % respectively , finely the interferences of some ions were studied.
American Psychological Association (APA)
al-Mutawalli, Nahlah Fatihe& Risan, Lamya Abd al-Latif& Abd al-Sahib, Maha. 2012. Study about complex formed between lanthanium (III) and organic reagent 2-[(4-bromo) phenyl azo]-4, 5-diphenyl imidazole. Journal of Kufa for Chemical Science،Vol. 2012, no. 5, pp.89-97.
https://search.emarefa.net/detail/BIM-307224
Modern Language Association (MLA)
al-Mutawalli, Nahlah Fatihe…[et al.]. Study about complex formed between lanthanium (III) and organic reagent 2-[(4-bromo) phenyl azo]-4, 5-diphenyl imidazole. Journal of Kufa for Chemical Science No. 5 (Jun. 2012), pp.89-97.
https://search.emarefa.net/detail/BIM-307224
American Medical Association (AMA)
al-Mutawalli, Nahlah Fatihe& Risan, Lamya Abd al-Latif& Abd al-Sahib, Maha. Study about complex formed between lanthanium (III) and organic reagent 2-[(4-bromo) phenyl azo]-4, 5-diphenyl imidazole. Journal of Kufa for Chemical Science. 2012. Vol. 2012, no. 5, pp.89-97.
https://search.emarefa.net/detail/BIM-307224
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 97
Record ID
BIM-307224
