Hydrolysis of thallium phthalimide. the crystal structure of dimorph polymeric thallium (I)‎ complex, {Tl [(hphthalate)‎]} n

Abstract EN

Single crystals of [Tl (Hphthalate)]n, were grown by hydrolysis of thallium phthalimide during slow evaporation of an aqueous solution at room temperature, and the structure was determined by X-ray diffraction analysis.

It has been characterized also by elemental analysis, NMR, and IR spectroscopy.

The crystals belong to the monoclinic crystal system space group P21 / c.

its crystal structure analysis reveals that there is (TlO6) six coordinate Tl atoms.

In addition, the coordination geometry of Tl + may be influenced by its stereo chemically active lone pair.

The complex is linked via intermolecular O-H•••O hydrogen bonding.