Polycondensation of acidanhydrides with aspargenyl imide diamine and curing with styrene as smart polymers

Joint Authors

Ahmad, M. A.
Ali, Firyal M.
Asil Q. M.

Source

Iraqi National Journal of Chemistry

Issue

Vol. 2012, Issue 46 (30 Jun. 2012), pp.250-259, 10 p.

Publisher

University of Babylon College of Sciences

Publication Date

2012-06-30

Country of Publication

Iraq

No. of Pages

10

Main Subjects

Chemistry

Abstract AR

حضر في هذا البحث البوليمرات التكاثفية الجديدة من تفاعل الحوامض اللامائية مثل حامض الماليئيك أو مثيل نادك اللامائي مع –N أسبارجنيل أيمايد داي أمين المحضر من تفاعل الأسبارجنيل كلورايد مع الأمونيا.

إن نسبة التحويل المئوية للبوليمر التكاثفي المحضر كانت نسبة عالية. قيست الصفات الفيزياوية و شخصت المونومرات و البوليمرات المحضرة بواسطة مطياف الأشعة فوق البنفسجية و الأشعة تحت الحمراء و قيست اللزوجة الجوهرية و أجري التحليل الحراري للبوليمرات المحضرة. إن إدخال الأسبارجين كحامض أميني في السلسلة البوليمرية ساعدت على صفة التحلل البايولوجي. و إن البوليمر المحضر الفعال بايولوجيا يمكن استعماله لتطبيقات مختلفة، و الذي يمكن استعماله كبوليمر ذكي نتيجة تحسسه للدالة الحامضية في أوساط مختلفة.

Abstract EN

In this paper some new condensed polymers were synthesized from reacting of unsaturated acid anhydride such as maleic or methylnadicanhydrides, with Naspargenyl imide diamine, which was prepared from reacting of aspargenyl chloride with ammonia.

The new condensed polymers were cured with styrene and the cross linked polymers were obtained with high percent conversion.

The physical properties of these polymer were measured .

The monomers and the corresponding polymers were characterized by FT-IR and UV.

spectroscopy.

The intrinsic viscosity was calculated and swelling% was studied for the prepared cross linked polymers.

The inserted aspargen as amino acid could enhance the biodegradability properties, and the prepared polymers can be used as biomaterial in different applications, such as smart polymers due to their sensitivity to pH change.

American Psychological Association (APA)

Ali, Firyal M.& Ahmad, M. A.& Asil Q. M.. 2012. Polycondensation of acidanhydrides with aspargenyl imide diamine and curing with styrene as smart polymers. Iraqi National Journal of Chemistry،Vol. 2012, no. 46, pp.250-259.
https://search.emarefa.net/detail/BIM-316312

Modern Language Association (MLA)

Ali, Firyal M.…[et al.]. Polycondensation of acidanhydrides with aspargenyl imide diamine and curing with styrene as smart polymers. Iraqi National Journal of Chemistry No. 46 (Jun. 2012), pp.250-259.
https://search.emarefa.net/detail/BIM-316312

American Medical Association (AMA)

Ali, Firyal M.& Ahmad, M. A.& Asil Q. M.. Polycondensation of acidanhydrides with aspargenyl imide diamine and curing with styrene as smart polymers. Iraqi National Journal of Chemistry. 2012. Vol. 2012, no. 46, pp.250-259.
https://search.emarefa.net/detail/BIM-316312

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references : p. 259

Record ID

BIM-316312