Synthesis and characterization of a new Schiff Base {N-(2-{[(4- bromophenyl)‎imino]methyl}phenyl)‎acetamide} and its complexes with some transition metal

Abstract EN

A new ligand {N-(2-{[(4-bromophenyl)imino]methyl}phenyl)acetamide} (L) and it complexes with Cr(III), Fe(III), Co(II), Ni(II) and Cu(II) were synthesized .

These compounds were identified by elemental analysis , Molar conductivity, as well as spectroscopic methods (IR, 1 HNMR ,Mass) .

It may be concluded that the ligand coordinate through Nitrogen atoms for all the complexes and act as a bidentate ligand which bond through –C=N and –NH groups ,This view is further supported by the appearance of a band corresponding to the metal – nitrogen stretching vibration at (524-550) Cm -1 in the complexes .

On the bases of these studies we suggest formation octahedral geometry for all preparded complexes .