Synthesis of substituted cyclohexenones from the condensation of acetone with 1, 3-diaryl-2-propen-1-one part 1

Author

al-Hamdani, Abd al-Wahhab J.

Source

al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah

Issue

Vol. 23, Issue 4 (31 Dec. 2010), pp.27-35, 9 p.

Publisher

University of Mosul College of Education for Pure Science

Publication Date

2010-12-31

Country of Publication

Iraq

No. of Pages

9

Main Subjects

Chemistry

Abstract AR

تم استعمال تكاثف كليزن-شميدت لتحضير سلسلة من 1,3- ثنائي اريل -2- بروبين -1- ون (10-1) تحت ظروف قاعدية.

و قد تم تكثيف الجالكونات (10-1) مع الاسيتون لإعطاء الهكسينونات الحلقية المقابلة (20-11).

تم تشخيص تراكيب النواتج النهائية في ضوء الطرائق الطيفية المتاحة (IR,UV) فضلا عن الكشوفات التقليدية في التشخيص العضوي.

فضلا عن ذلك تم استعمال الحسابات النظرية لحرارة التكوين H.F و طاقة الإعاقة S.E لدعم ميكانيكية التفاعل المقترحة.

Abstract EN

Claisen-Schmidt condensation had been used to prepare a series of 1, 3-Diaryl-2-propen-1-one (1-10), under strong basic condations.

The prepared chalcones (1-10) were condensed with acetone to afford the corresponding cyclohexenones (11-20).

The structures of the final products had been identified in the light of valid spectral methods (U.V., I.R.) as well as the typical identification tests .In addition, to the theoretical calculations of heat of formation H.F.

and Steric energy S.E.

were used to support the suggested reaction mechanism.

American Psychological Association (APA)

al-Hamdani, Abd al-Wahhab J.. 2010. Synthesis of substituted cyclohexenones from the condensation of acetone with 1, 3-diaryl-2-propen-1-one part 1. al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah،Vol. 23, no. 4, pp.27-35.
https://search.emarefa.net/detail/BIM-325701

Modern Language Association (MLA)

al-Hamdani, Abd al-Wahhab J.. Synthesis of substituted cyclohexenones from the condensation of acetone with 1, 3-diaryl-2-propen-1-one part 1. al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah Vol. 23, no. 4 (2010), pp.27-35.
https://search.emarefa.net/detail/BIM-325701

American Medical Association (AMA)

al-Hamdani, Abd al-Wahhab J.. Synthesis of substituted cyclohexenones from the condensation of acetone with 1, 3-diaryl-2-propen-1-one part 1. al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah. 2010. Vol. 23, no. 4, pp.27-35.
https://search.emarefa.net/detail/BIM-325701

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references : p. 35

Record ID

BIM-325701