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Synthesis of substituted cyclohexenones from the condensation of acetone with 1, 3-diaryl-2-propen-1-one part 1
Author
Source
al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah
Issue
Vol. 23, Issue 4 (31 Dec. 2010), pp.27-35, 9 p.
Publisher
University of Mosul College of Education for Pure Science
Publication Date
2010-12-31
Country of Publication
Iraq
No. of Pages
9
Main Subjects
Abstract AR
تم استعمال تكاثف كليزن-شميدت لتحضير سلسلة من 1,3- ثنائي اريل -2- بروبين -1- ون (10-1) تحت ظروف قاعدية.
و قد تم تكثيف الجالكونات (10-1) مع الاسيتون لإعطاء الهكسينونات الحلقية المقابلة (20-11).
تم تشخيص تراكيب النواتج النهائية في ضوء الطرائق الطيفية المتاحة (IR,UV) فضلا عن الكشوفات التقليدية في التشخيص العضوي.
فضلا عن ذلك تم استعمال الحسابات النظرية لحرارة التكوين H.F و طاقة الإعاقة S.E لدعم ميكانيكية التفاعل المقترحة.
Abstract EN
Claisen-Schmidt condensation had been used to prepare a series of 1, 3-Diaryl-2-propen-1-one (1-10), under strong basic condations.
The prepared chalcones (1-10) were condensed with acetone to afford the corresponding cyclohexenones (11-20).
The structures of the final products had been identified in the light of valid spectral methods (U.V., I.R.) as well as the typical identification tests .In addition, to the theoretical calculations of heat of formation H.F.
and Steric energy S.E.
were used to support the suggested reaction mechanism.
American Psychological Association (APA)
al-Hamdani, Abd al-Wahhab J.. 2010. Synthesis of substituted cyclohexenones from the condensation of acetone with 1, 3-diaryl-2-propen-1-one part 1. al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah،Vol. 23, no. 4, pp.27-35.
https://search.emarefa.net/detail/BIM-325701
Modern Language Association (MLA)
al-Hamdani, Abd al-Wahhab J.. Synthesis of substituted cyclohexenones from the condensation of acetone with 1, 3-diaryl-2-propen-1-one part 1. al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah Vol. 23, no. 4 (2010), pp.27-35.
https://search.emarefa.net/detail/BIM-325701
American Medical Association (AMA)
al-Hamdani, Abd al-Wahhab J.. Synthesis of substituted cyclohexenones from the condensation of acetone with 1, 3-diaryl-2-propen-1-one part 1. al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah. 2010. Vol. 23, no. 4, pp.27-35.
https://search.emarefa.net/detail/BIM-325701
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 35
Record ID
BIM-325701