Dinuclear tungsten and molybdenum tetracarbonyl complexes doubly-bridged by bis (phenylthio) alkane bidentate ligands
Joint Authors
al-Said, Naim H.
Asali, Khalil J.
Source
Issue
Vol. 8, Issue 1 (31 Mar. 2013), pp.57-62, 6 p.
Publisher
Yarmouk University Deanship of Research and Graduate Studies
Publication Date
2013-03-31
Country of Publication
Jordan
No. of Pages
6
Main Subjects
Abstract EN
A new series of dinuclear group 6 metal tetracarbonyl complexes containing two Bis (phenylthio) alkane ligands symmetrically bridging two M (CO) 4 moieties of the type cis- {[M (CO)4] 2(μ-PhS (CH2) nSPh)2} [M = W (1), Mo (2) ; n = 3 (a), 4 (b), 5 (c), 6 (d)] have been prepared by the reaction of the labile complex M(CO)4 (py) 2 and bis(phenylthio) alkanes (1:1 molar ratio) in 1, 2-dichloroethane solution under mild reaction conditions.
The tungsten complexes are air stable as solids and in chlorinated hydrocarbon solution.
In contrast, the Mo analogues are air sensitive as solids and should be stored under inert atmosphere.
American Psychological Association (APA)
Asali, Khalil J.& al-Said, Naim H.. 2013. Dinuclear tungsten and molybdenum tetracarbonyl complexes doubly-bridged by bis (phenylthio) alkane bidentate ligands. Jordan Journal of Chemistry،Vol. 8, no. 1, pp.57-62.
https://search.emarefa.net/detail/BIM-326159
Modern Language Association (MLA)
Asali, Khalil J.& al-Said, Naim H.. Dinuclear tungsten and molybdenum tetracarbonyl complexes doubly-bridged by bis (phenylthio) alkane bidentate ligands. Jordan Journal of Chemistry Vol. 8, no. 1 (Mar. 2013), pp.57-62.
https://search.emarefa.net/detail/BIM-326159
American Medical Association (AMA)
Asali, Khalil J.& al-Said, Naim H.. Dinuclear tungsten and molybdenum tetracarbonyl complexes doubly-bridged by bis (phenylthio) alkane bidentate ligands. Jordan Journal of Chemistry. 2013. Vol. 8, no. 1, pp.57-62.
https://search.emarefa.net/detail/BIM-326159
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 62
Record ID
BIM-326159