Synthesis and characterization of some complexes of Mn (II), Fe(II), Co(II), Ni(II), Cu(II) and Zn (II)withBis-(2, 3-Dimethoxybenzylidene) thiosemicarbazone
Author
Source
Iraqi National Journal of Chemistry
Issue
Vol. 2013, Issue 49 (31 Mar. 2013), pp.73-85, 13 p.
Publisher
University of Babylon College of Sciences
Publication Date
2013-03-31
Country of Publication
Iraq
No. of Pages
13
Main Subjects
Topics
Abstract AR
تم تحضير عدد من المعقدات الجديدة ذوات الصيغة العامة [ML2C2] و [ML2(bip)]Cl2 {حيث L = ثنائي -(2, 3- ثاني ميثوكسيبنزليدين) ثايوسيميكارابازون, M = Mn(II) و Fe(II) و Co(II) و Ni(II) و Cu(II) و Zn(II), =bip ثاني البيريدايل}.
تم تشخيص المعقدات المحضرة بوساطة قياسات التوصيلية الكهربائية و المغناطيسية و أطياف الأشعة تحت الحمراء و الأطياف الإلكترونية و التحليل الدقيق للعناصر CHN و تعيين المحتوى الفلزي.
و قد بينت دراسة الأطياف الإلكترونية و قياسات العزوم المغناطيسية بأن معقدات (Fe(II),Mn(IICo(II),Cu(II),Ni(II), و Zn(II)) تمتلك بنية تركيبية ثماني السطوح.
Abstract EN
A number of new complexes of the general formulaes [ML2Cl2] and [ML2 (bip)] Cl2 {where L = bis-(2, 3 Dimethoxybenzylidene)thiosemcarbazone ; M = Mn (II), Fe (II), Co (II), Ni (II), Cu (II) and Zn (II), bip = bipyridyl}were prepared and characterized by molar conductance, magnetic properties, infrared, electronic spectra, metal contents, and CHN analysis.
The electronic spectra study and magnetic moments measurements indicated that the Mn (II), Fe (II), Co (II), Ni (II), Cu (II) and Zn (II) complexes have an octahedral geometry.
American Psychological Association (APA)
al-Sabawi, Sahbaa Ali Ahmad. 2013. Synthesis and characterization of some complexes of Mn (II), Fe(II), Co(II), Ni(II), Cu(II) and Zn (II)withBis-(2, 3-Dimethoxybenzylidene) thiosemicarbazone. Iraqi National Journal of Chemistry،Vol. 2013, no. 49, pp.73-85.
https://search.emarefa.net/detail/BIM-330537
Modern Language Association (MLA)
al-Sabawi, Sahbaa Ali Ahmad. Synthesis and characterization of some complexes of Mn (II), Fe(II), Co(II), Ni(II), Cu(II) and Zn (II)withBis-(2, 3-Dimethoxybenzylidene) thiosemicarbazone. Iraqi National Journal of Chemistry No. 49 (Mar. 2013), pp.73-85.
https://search.emarefa.net/detail/BIM-330537
American Medical Association (AMA)
al-Sabawi, Sahbaa Ali Ahmad. Synthesis and characterization of some complexes of Mn (II), Fe(II), Co(II), Ni(II), Cu(II) and Zn (II)withBis-(2, 3-Dimethoxybenzylidene) thiosemicarbazone. Iraqi National Journal of Chemistry. 2013. Vol. 2013, no. 49, pp.73-85.
https://search.emarefa.net/detail/BIM-330537
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 84-85
Record ID
BIM-330537
