Solvent extraction and spectrophotomteric determination of Cu (Ii)‎ with dicyclohexyl-18-crown-6

Other Title(s)

الاستخلاص المذيبي للنحاس بوساطة داي سايكلو هيكسل-18-كروان-6- و تعينة بتقنية المطيافية الضوئية

Author

Muhammad, Suad Salman

Source

Baghdad Science Journal

Issue

Vol. 10, Issue 3 (30 Sep. 2013), pp.997-1004, 8 p.

Publisher

University of Baghdad College of Science for Women

Publication Date

2013-09-30

Country of Publication

Iraq

No. of Pages

8

Main Subjects

Chemistry

Topics

Abstract AR

تم استخدام طريقة الاستخلاص بالمذيب لتعين النحاس في الوسط المائي بطريقة لونية باستعمال الكاشف dicyclohexyl-18-crown-6 المذاب في الدايكلوروايثان و الذي كون معقد ملون.

استخلص في دالة حامضية 6.3.

قانون بير وجد مطاوعا في مدى تراكيز (2.5-22.5) ملغم / لتر بمعامل ارتباط 0.9989 و امتصاصية مولارية 1 x104 لتر مول1-.

سم1- و وجد أن المعقد المستخلص ذات تركيب محتمل هو (1:2).

Abstract EN

Liquid-Liquid Extraction of Cu(II) ion in aqueous solution by dicyclohexyl-18-crown-6 as extractant in dichloroethane was studied .The extraction efficiency was investigated by a spectrophometric method. The reagent form a coloured complex which has been a quantitatively extracted at pH 6.3.

The method obeys Beer`s law over range from (2.5-22.5) ppm with the correlation coefficient of 0.9989.

The molar absorptivity the stoichiometry of extracted complex is found to be 1 : 2.

the proposed method is very sensitive and selective.

American Psychological Association (APA)

Muhammad, Suad Salman. 2013. Solvent extraction and spectrophotomteric determination of Cu (Ii) with dicyclohexyl-18-crown-6. Baghdad Science Journal،Vol. 10, no. 3, pp.997-1004.
https://search.emarefa.net/detail/BIM-343205

Modern Language Association (MLA)

Muhammad, Suad Salman. Solvent extraction and spectrophotomteric determination of Cu (Ii) with dicyclohexyl-18-crown-6. Baghdad Science Journal Vol. 10, no. 3 (2013), pp.997-1004.
https://search.emarefa.net/detail/BIM-343205

American Medical Association (AMA)

Muhammad, Suad Salman. Solvent extraction and spectrophotomteric determination of Cu (Ii) with dicyclohexyl-18-crown-6. Baghdad Science Journal. 2013. Vol. 10, no. 3, pp.997-1004.
https://search.emarefa.net/detail/BIM-343205

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references : p. 1003

Record ID

BIM-343205