Synthesis and characterization complexes of Zn (II)‎, Cd (II)‎, Hg (II)‎ with new schiff base derivative of 4-amino antipyrine with ethylene diamine

Joint Authors

Ghanim, Hasan T.
Muhammad, Mithak S.
Kazim, Afak J.

Source

Journal of Babylon University : Journal of Applied and Pure Sciences

Issue

Vol. 21, Issue 5 (31 Mar. 2013), pp.1674-1680, 7 p.

Publisher

University of Babylon

Publication Date

2013-03-31

Country of Publication

Iraq

No. of Pages

7

Main Subjects

Chemistry

Abstract AR

مع ليكاند قاعدة شف المشتقة من 4 – (II) و الزئبق (II) و الكادميوم (II) تضمن البحث تحضير المعقدات لأيونات الخارصين امينو انتييبيرين و 3 – هيدروكسي بنزلديهايد و أثلين ثنائي الأمين.

شخصت المعقدات بوساطة التحليل الدقيق للعناصر و طيف الأشعة تحت الحمراء بالإضافة إلى التوصيلية المولارية و الأطياف الإلكترونية.

بينت نتائج الدراسة أن الليكاند يسلك كليكاند ثلاثية المخلب من تم اقتراح الصيغة التركيبية ثمانية السطوح.

(2:1) و ترتبط مع الأيونات الفلزية مولية (C=N) خلال مجموعة فلز : ليكاند.

Abstract EN

Anew metal complexes of Zn (II), Cd (II) and Hg (II) were synthesized from the Schiff base derived from 4-amino antipyrine, 3-hydroxyl benzaldehyde and ethylene diamine in alcohol medium.

All the complexes were characterized on the basis of their elemental analysis, molar conductance, in addition FTIR and electronic spectra.

The result show that the functional groups was (-C=N).

It has been found that the Schiff base ligand behaves as a tridentate ligand forming chelates with 1:2 (metal : ligand) stoichiometry.

The suggest geometry of the complexes appears to be octahedral.

American Psychological Association (APA)

Muhammad, Mithak S.& Ghanim, Hasan T.& Kazim, Afak J.. 2013. Synthesis and characterization complexes of Zn (II), Cd (II), Hg (II) with new schiff base derivative of 4-amino antipyrine with ethylene diamine. Journal of Babylon University : Journal of Applied and Pure Sciences،Vol. 21, no. 5, pp.1674-1680.
https://search.emarefa.net/detail/BIM-346373

Modern Language Association (MLA)

Kazim, Afak J.…[et al.]. Synthesis and characterization complexes of Zn (II), Cd (II), Hg (II) with new schiff base derivative of 4-amino antipyrine with ethylene diamine. Journal of Babylon University : Journal of Applied and Pure Sciences Vol. 21, no. 5 (2013), pp.1674-1680.
https://search.emarefa.net/detail/BIM-346373

American Medical Association (AMA)

Muhammad, Mithak S.& Ghanim, Hasan T.& Kazim, Afak J.. Synthesis and characterization complexes of Zn (II), Cd (II), Hg (II) with new schiff base derivative of 4-amino antipyrine with ethylene diamine. Journal of Babylon University : Journal of Applied and Pure Sciences. 2013. Vol. 21, no. 5, pp.1674-1680.
https://search.emarefa.net/detail/BIM-346373

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references : p. 1679-1680

Record ID

BIM-346373