Synthesis and characterization of bimetallic complexes of the type [L2 Pd (µ-dppm) 2MXn] ; (MXn = MnCI2, CuCl2, PtCI2, PdCl2, SnCI4 and Mo (CO)4, L = deprotonated 4, 5- diphenyl- 1, 2, 4- triazole-3 thione and dppm = bis (diphenylphosphino) methane
Author
Source
Issue
Vol. 2006, Issue 23 (30 Sep. 2006), pp.368-378, 11 p.
Publisher
University of Babylon College of Sciences
Publication Date
2006-09-30
Country of Publication
Iraq
No. of Pages
11
Main Subjects
Abstract AR
معاملة [PdL2]-cis مع dppm بنسبة (1 : 2) أعطت المعقد [PdL 2 (dppm) 2].
كذلك تفاعل المعقد [PdL 2 (dppm) 2] مع بعض عناصر انتقالية في الكلوروفورم اعطت معقدات ثنائية الفلز من نوع [L 2 Pd (u-dppm)2 MXN ] : حيث أن (MXN = MNCI2, CUCI2, PtCI2, PdCI2, SnCI4, Mo(CO) 4).
تم تشخيص معقدات ثنائية الفلز المحضرة بواسطة التحليل الدقيق للعناصر و أطياف IR و UV.
/ Vis.
و توصيل الكهربائي المولي و قياسات الحساسية المغناطيسية.
Abstract EN
Treatment of cis-[ PdL2 ] with dppm (1:2) gave the complex [ PdL2 (dppm)2 ] .
Reaction of the [ PdL2 (dppm)2 ] with some transition metals in chloroform yielded bimetallic complexes of the type [ L2 Pd( µ-dppm)2MXn ] ; where ( MXn = MnCI2 ,CuCl2 , PtCI2 , PdCl2 , SnCI4 and Mo(CO)4 ) .
The prepared bimetallic complexes were characterized by elemental analysis , infrared , UV./ Vis.
, molar conductance , magnetic susceptibility measurement .
American Psychological Association (APA)
Abd Allah, Bayazid H.. 2006. Synthesis and characterization of bimetallic complexes of the type [L2 Pd (µ-dppm) 2MXn] ; (MXn = MnCI2, CuCl2, PtCI2, PdCl2, SnCI4 and Mo (CO)4, L = deprotonated 4, 5- diphenyl- 1, 2, 4- triazole-3 thione and dppm = bis (diphenylphosphino) methane. National Journal of Chemistry،Vol. 2006, no. 23, pp.368-378.
https://search.emarefa.net/detail/BIM-348880
Modern Language Association (MLA)
Abd Allah, Bayazid H.. Synthesis and characterization of bimetallic complexes of the type [L2 Pd (µ-dppm) 2MXn] ; (MXn = MnCI2, CuCl2, PtCI2, PdCl2, SnCI4 and Mo (CO)4, L = deprotonated 4, 5- diphenyl- 1, 2, 4- triazole-3 thione and dppm = bis (diphenylphosphino) methane. National Journal of Chemistry No. 23 (2006), pp.368-378.
https://search.emarefa.net/detail/BIM-348880
American Medical Association (AMA)
Abd Allah, Bayazid H.. Synthesis and characterization of bimetallic complexes of the type [L2 Pd (µ-dppm) 2MXn] ; (MXn = MnCI2, CuCl2, PtCI2, PdCl2, SnCI4 and Mo (CO)4, L = deprotonated 4, 5- diphenyl- 1, 2, 4- triazole-3 thione and dppm = bis (diphenylphosphino) methane. National Journal of Chemistry. 2006. Vol. 2006, no. 23, pp.368-378.
https://search.emarefa.net/detail/BIM-348880
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 377-378
Record ID
BIM-348880
