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Study of charge transfer complexes of salicylideneanilines and its substituents with pr (fod) 3 in cyclohexane by U. V. spectroscopy
Other Title(s)
دراسة معقدات انتقال الشحنة لمركبات السالسدين أنيلين ومعوضاته مع Pr (fod) 3 في مذيب السايكلوهكسان بمطيافية الأشعة فوق البنفسجية
Source
Issue
Vol. 17, Issue 4/S (31 Jul. 2006), pp.63-67, 5 p.
Publisher
University of Mosul College of Science
Publication Date
2006-07-31
Country of Publication
Iraq
No. of Pages
5
Main Subjects
Abstract EN
Salicylidene aniline and its substituents form 1:1 charge transfer complexes with the lanthanide shift reagent Pr(fod)3 in cyclohexane indicated by the observation of a new band in their U.V.
spectra located at longer wavelength (λmax = 430 nm) and with its low extinction coefficient.
The colourless solutions of Schiff’s-bases were changed to yellow on complexation with Pr(fod)3.
Equilibrium constant values (K) for the complexes were calculated by applying Benesi-Hildebrand equation at different temperatures, and the thermodynamic parameters ΔH, ΔS and ΔG were obtained.
Negative values of ΔG indicates that the complexation occurs spontaneously.
Application of Hammet equation on K values for the para substituents show straight line with negative slope indicating that the electron donating groups enhances the reaction of complexation
American Psychological Association (APA)
Salim, Layla M.& al-Dabbagh, Mayy G.. 2006. Study of charge transfer complexes of salicylideneanilines and its substituents with pr (fod) 3 in cyclohexane by U. V. spectroscopy. Rafidain Journal of Science،Vol. 17, no. 4/S, pp.63-67.
https://search.emarefa.net/detail/BIM-351868
Modern Language Association (MLA)
Salim, Layla M.& al-Dabbagh, Mayy G.. Study of charge transfer complexes of salicylideneanilines and its substituents with pr (fod) 3 in cyclohexane by U. V. spectroscopy. Rafidain Journal of Science Vol. 17, no. 4 (2006), pp.63-67.
https://search.emarefa.net/detail/BIM-351868
American Medical Association (AMA)
Salim, Layla M.& al-Dabbagh, Mayy G.. Study of charge transfer complexes of salicylideneanilines and its substituents with pr (fod) 3 in cyclohexane by U. V. spectroscopy. Rafidain Journal of Science. 2006. Vol. 17, no. 4/S, pp.63-67.
https://search.emarefa.net/detail/BIM-351868
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 66-67
Record ID
BIM-351868