Synthesis and characterization and biological activity of some new mannich basesand their metal complexes with (Cd2+, Ni2+ and Mn2+)
Joint Authors
al-Jamali, Nagham Mahmud
Abd al-Amir, Raja
Jabir, Afaq Kazim
Source
Iraqi National Journal of Chemistry
Issue
Vol. 2013, Issue 50 (30 Jun. 2013), pp.128-140, 13 p.
Publisher
University of Babylon College of Sciences
Publication Date
2013-06-30
Country of Publication
Iraq
No. of Pages
13
Main Subjects
Abstract AR
تضمن هذا البحث تخليق خمسة مركبات جديدة من قواعد مانخ من خلال التفاعل ببن مركبات ثنائية الكيتون مع الأمونيا أو مشتقات الأمين لتعطي وسيط كيتون الأينامين و الذي بدوره يتفاعل مع مركبات الألدهايد لتنتج المركبات [1-5]، و المركب [5] يتفاعل بدوره مع ايونات (Cd2+, Ni2+, Mn2+) لتكوين المعقدات [6-8].
شُخُصت المركبات المحضرة باستخدام تقنية (التحليل الكمي الدقيق للعناصر، طيف الرنين النووي المغناطيسي، طيف الأشعة تحت الحمراء) تكافؤية المعقدات، التوصيلية المولاریة، نقاط الانصهار مع دراسة بایولوجیة للمعقدات.
النتائج المستحصلة دليل قاطع للمركبات المحضرة [1-8].
Abstract EN
In this work, five new compounds of mannich bases were synthesized by the reaction between diketone compounds and ammonia or amine derivatives to give enamino ketone as intermediate, which may react with aldehydes to yiled compounds [1-5], and complexes [6-8], mannich base [5] reacts with transition metal ions (Cd+2, Ni+2 and Mn+2), to form complexes of the type [6-8].
The synthesized compounds [1-8] are characterized by {(C.H.N)–analysis, 1HNMR-spectra, FT.IR-spectra}, stochiometric study, molar conductance, melting points, biological study.
The data obtained gave good support for synthesized compounds [1-8].
American Psychological Association (APA)
al-Jamali, Nagham Mahmud& Abd al-Amir, Raja& Jabir, Afaq Kazim. 2013. Synthesis and characterization and biological activity of some new mannich basesand their metal complexes with (Cd2+, Ni2+ and Mn2+). Iraqi National Journal of Chemistry،Vol. 2013, no. 50, pp.128-140.
https://search.emarefa.net/detail/BIM-356562
Modern Language Association (MLA)
al-Jamali, Nagham Mahmud…[et al.]. Synthesis and characterization and biological activity of some new mannich basesand their metal complexes with (Cd2+, Ni2+ and Mn2+). Iraqi National Journal of Chemistry No. 50 (Jun. 2013), pp.128-140.
https://search.emarefa.net/detail/BIM-356562
American Medical Association (AMA)
al-Jamali, Nagham Mahmud& Abd al-Amir, Raja& Jabir, Afaq Kazim. Synthesis and characterization and biological activity of some new mannich basesand their metal complexes with (Cd2+, Ni2+ and Mn2+). Iraqi National Journal of Chemistry. 2013. Vol. 2013, no. 50, pp.128-140.
https://search.emarefa.net/detail/BIM-356562
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 140
Record ID
BIM-356562
