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Synthesis and identification of series from new ligands derived from 5, 6-diformyl-4-chloro methoxy benzene and complexation of one of them with (Zn2+, Cd2+)
Author
al-Ghurabi, Fatimah Abd Wannas
Source
Iraqi National Journal of Chemistry
Issue
Vol. 2013, Issue 51 (30 Sep. 2013), pp.316-326, 11 p.
Publisher
University of Babylon College of Sciences
Publication Date
2013-09-30
Country of Publication
Iraq
No. of Pages
11
Main Subjects
Topics
Abstract AR
تضمنت الدراسة تحضير أربع ليكاندات من تفاعل 6, 2 ثنائي فورميل-4-كلورو-ميثوكسي بنزين مع مركبات أمين مختلفة تمثلت ب 2-)أمينوفيوران،2- أمينو ثايوفين ، 2-أمینو ثیازول ،2- أمينو سلفادیازین) لینتج لیكاندات [1-4]، سُمیت اللیكاندات المحضرة ب {N,N--(5-Chloro-2-Methoxy-1,3-phenylene) bis(Methan-1-yl- ylidene)dithiophen-2-amine (FCM),N,N--(5-Chloro-2-Methoxy-1,3- phenylene) bis(Methan-1-yl-ylidene) difuran-2-amine(TCM), N,N-- (5-Chloro-2-Methoxy-1,3-phenylene) bis (Methan-1-yl -ylidene) dithiazol-2-amine(ZCM),N,N--(5-Chloro-2-Methoxy-1,3-phenylene) bis (Methan-1-yl-ylidene) (SCM)} على التوالي.
المركب (ZCM) استخدم كليكاند مع أيوني، (Zn2+, Cd2+) لتكوين معقدات و دراسة الظروف المثلى لتعقيدها (تكافؤ المعقبدات، الدالة الحامضية، تركيز الليكاند و الأيونين، التوصيلية المولارية، النسب المولية) جميع الليكاندات المحضرة و المعقدات درست فعاليتها البكتيرية و الفطرية و كذالك، شخصت بتقنيات ( طيف الأشعة تحت الحمراء، طيف الرنين النووي المغناطيسي، التحليل الدقيق للعناصر، الأشعة الفوق البنفسجية و المرئية) و درجات الإنصهار.
Abstract EN
In this study, four ligands were synthesized from reaction of 2, 6-diformyl-4-chloro methoxy benzene with different amino compounds such as(2-amino furan, 2-amino thiophene, 2-amino thiazole, 2-amino sulphadiazine) to produce ligands [1-4], the synthesized ligands is named {N, N--(5-Chloro-2-Methoxy-1, 3-phenylene)bis (Methan-1-yl-ylidene)dithiophen-2-amine(FCM), N, N--(5-Chloro-2-Methoxy-1, 3- phenylene)bis(Methan-1-yl-ylidene)difuran-2-amine (TCM), N, N-- (5-Chloro-2- Methoxy-1, 3-phenylene)bis (Methan-1-yl-ylidene)dithiazol-2-amine (ZCM), N, N-- (5-Chloro-2-Methoxy-1, 3-phenylene) bis(Methan-1-yl-ylidene) (SCM)} respectively.
The ligand (ZCM) is used as a ligand with (Zn2+, Cd2+) to formation of complexes and study of optimal conditions of complexes (stoichiometric study, pH, concentration of metals and ligand, molar conductance).
All ligands with complexes were studied for antibacterial and antifungi activity.
All ligands with complexes were characterized by (H.NMR–spectra, FT.IR–spectra (C.H.N)-analysis, UV-Vib-spectra), melting points.
American Psychological Association (APA)
al-Ghurabi, Fatimah Abd Wannas. 2013. Synthesis and identification of series from new ligands derived from 5, 6-diformyl-4-chloro methoxy benzene and complexation of one of them with (Zn2+, Cd2+). Iraqi National Journal of Chemistry،Vol. 2013, no. 51, pp.316-326.
https://search.emarefa.net/detail/BIM-356584
Modern Language Association (MLA)
al-Ghurabi, Fatimah Abd Wannas. Synthesis and identification of series from new ligands derived from 5, 6-diformyl-4-chloro methoxy benzene and complexation of one of them with (Zn2+, Cd2+). Iraqi National Journal of Chemistry No. 51 (Sep. 2013), pp.316-326.
https://search.emarefa.net/detail/BIM-356584
American Medical Association (AMA)
al-Ghurabi, Fatimah Abd Wannas. Synthesis and identification of series from new ligands derived from 5, 6-diformyl-4-chloro methoxy benzene and complexation of one of them with (Zn2+, Cd2+). Iraqi National Journal of Chemistry. 2013. Vol. 2013, no. 51, pp.316-326.
https://search.emarefa.net/detail/BIM-356584
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 326
Record ID
BIM-356584