Synthesis of some 2,4-hexadiyne and their polymers
Author
Source
Issue
Vol. 2005, Issue 18 (30 Jun. 2005), pp.261-271, 11 p.
Publisher
University of Babylon College of Sciences
Publication Date
2005-06-30
Country of Publication
Iraq
No. of Pages
11
Main Subjects
Abstract AR
يتضمن البحث تحضير عدد من المركبات ثنائية الاستيلين و قد جرى تعريض هذه المركبات (و التي تمثل مونومرات) لأشعة كاما حيث تحول المركب (4) إلى البوليمر المقابل بينما لن تنجح المركبات (c-3a) بسبب عدم توفر ظروف البلمرة بسبب تركيب هذه المونومرات الذي لا يتيح لها من الترتيب بشكل بلوري ترتيبا مناسبا لتقنية البلمرة بالحالة الصلبة.
كما تضمن البحث تحضير بولي اميدات (المركبات 6 و 7) عن طريق تقنية البلمرة التكثيفية و تم تشخيص المركبات أعلاه من خلال أطياف ال HNMR1 و CNMR13 و IR.
Abstract EN
Diacetylene monomers 2, 3 and 4 were synthesized using Hay coupling procedure.
They subjected to γ-ray irradiation resulted into polymer formation compound (8) while compounds (3a-c) were unsuccessful towrd topochemical polymerization.
The corresponding acid chloride compound (5) was then condensed with diamine affording polyamide 6 and 7.
The above symmetrically substituted 1,3-diynes together with their polymers have been characterized by combination of spectral methods IR,1HNMR, C13NMR and are discussed.
American Psychological Association (APA)
al-Ujayli, Muhammad Salman. 2005. Synthesis of some 2,4-hexadiyne and their polymers. National Journal of Chemistry،Vol. 2005, no. 18, pp.261-271.
https://search.emarefa.net/detail/BIM-362439
Modern Language Association (MLA)
al-Ujayli, Muhammad Salman. Synthesis of some 2,4-hexadiyne and their polymers. National Journal of Chemistry No. 18 (2005), pp.261-271.
https://search.emarefa.net/detail/BIM-362439
American Medical Association (AMA)
al-Ujayli, Muhammad Salman. Synthesis of some 2,4-hexadiyne and their polymers. National Journal of Chemistry. 2005. Vol. 2005, no. 18, pp.261-271.
https://search.emarefa.net/detail/BIM-362439
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 270-271
Record ID
BIM-362439
