2-Pentyne complexes of molybdenum (II) and tungsten (II)
Other Title(s)
مركبات تناسقية من 2-Pentyne مع الموليبدينوم (II) و التنجستن (II)
Author
Source
Journal of King Abdulaziz University : Sciences
Issue
Vol. 17, Issue 1 (31 Dec. 2005), pp.97-106, 10 p.
Publisher
King Abdulaziz University Scientific Publishing Center
Publication Date
2005-12-31
Country of Publication
Saudi Arabia
No. of Pages
10
Main Subjects
Abstract AR
إن التفاعل الكيميائي بين المركبات التناسقية مع المركبات العضوية التي تحمل الرابطة الثلاثية هي محل اهتمام اصطناع عضو فلزي، و من هذه المعقدات تفاعل [2(Ml2(CO)3(NCMe] (M = Mo, W) مع (2-Pentyne) لتعطي ( and 2) [MI2(CO)(NCMe1) [2EtC2Me2η) ثم يتم تفاعل المركبان ١ و ٢ مع متصلات أخرى مثل : PPh3 أو Ph2P(CH2)nPPh2 لتعطي على التوالي : [MI2(CO)(PPh3)2(η2-EtC2Me)] (3 and 4) & [MI2(CO){Ph2P (CH2)n PPh2}(η2-EtC2Me)] (for M = Mo, W, n = 1-4) (5-12).
Abstract EN
Treatment of [MI2(CO)3(NCMe)2](M = Mo, W) with two equivalents of EtC2Me in CH2Cl2 at 0Cº yields the bis (2- Pentyne) complexes [MI2(CO)(NCMe)(η2-EtC2Me)2] (1 and 2).
complexes.
1 and 2 react with two equivalents of PPh3 in CH2Cl2 to give the complexes [MI2 (CO) (PPh3)2 (η2-EtC2Me)] (3 and 4).
Reaction of 1 and 2 with an equimolar amount of Ph2P (CH2)n PPh2 to give [MI2(CO){(Ph2P(CH2)nPPh2}(η2-EtC2Me)] (for M = MO, W; n = 1-4) (5-12).
American Psychological Association (APA)
al-Jahdali, Mutlaq. 2005. 2-Pentyne complexes of molybdenum (II) and tungsten (II). Journal of King Abdulaziz University : Sciences،Vol. 17, no. 1, pp.97-106.
https://search.emarefa.net/detail/BIM-364964
Modern Language Association (MLA)
al-Jahdali, Mutlaq. 2-Pentyne complexes of molybdenum (II) and tungsten (II). Journal of King Abdulaziz University : Sciences Vol. 17, no. 1 ( 2005), pp.97-106.
https://search.emarefa.net/detail/BIM-364964
American Medical Association (AMA)
al-Jahdali, Mutlaq. 2-Pentyne complexes of molybdenum (II) and tungsten (II). Journal of King Abdulaziz University : Sciences. 2005. Vol. 17, no. 1, pp.97-106.
https://search.emarefa.net/detail/BIM-364964
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 104-105
Record ID
BIM-364964
