Synthesis and characterization of schiff-base ligand derivative from 4-aminoantipyrine and its transition metal complexes
Author
Source
Journal of Kufa for Chemical Science
Issue
Vol. 2013, Issue 8 (31 Dec. 2013), pp.70-78, 9 p.
Publisher
University of Kufa Faculty of Education for Women Department of Chemistry
Publication Date
2013-12-31
Country of Publication
Iraq
No. of Pages
9
Main Subjects
Abstract AR
تضمن هذا البحث تحضير أحد قواعد شيف و هو الليكاند الجديد ( 4- [(4- ثنائي مثيل - امينو بنزيلدين) امينو] -5, 1- ثنائي مثيل -2- فنيل 1, 2- ثنائي هايدرو - بيرزول -3- ون) حيث تم تحضيره من خلال التفاعل بين المركب 4- امينو انتبايرن مع 4- ثنائي مثيل امينو بنزالديهايد في محلول الايثانول النقي كما حضرت أربع معقدات مع الليكاند الجديد و هي معقدات Co (II), Zn (II), Cd (II), Hg (II) إذ أجرى تشخيص هذه المعقدات بواسطة أطياف FTIR و UV-visible و التحليل الطيفي للعناصر و تم تعيين النسب المولية (L:M) و النسبة المئوية للعنصر بالمطيافية الذرية اللهبي و قياس الحساسية المغناطيسية لهذه المعقدات.
Abstract EN
A new ligand 4-[(4-Dimethylamino-benzylidene)-amino]-1, 5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-one (L) was synthesized by the reaction of 4-aminoantipyrine with 4-Dimethylamino benzaldehyde in absolute ethanol.
The complexes of Co(II), Zn(II) Cd(II) and Hg(II) with this ligand have been prepared.
The characterization of ligand complexes are verify by elemental analysis, FT-IR, and UV / visible spectra.
Beside, the determination of mole ratio M : L for complexe, determination of metal content M % by flame atomic absorption spectroscopy, molar conductance in absolute ethanol and magnetic moments (μeff.) are presented.
American Psychological Association (APA)
Budaywi, Zaynab Muhsin. 2013. Synthesis and characterization of schiff-base ligand derivative from 4-aminoantipyrine and its transition metal complexes. Journal of Kufa for Chemical Science،Vol. 2013, no. 8, pp.70-78.
https://search.emarefa.net/detail/BIM-372765
Modern Language Association (MLA)
Budaywi, Zaynab Muhsin. Synthesis and characterization of schiff-base ligand derivative from 4-aminoantipyrine and its transition metal complexes. Journal of Kufa for Chemical Science No. 8 (Dec. 2013), pp.70-78.
https://search.emarefa.net/detail/BIM-372765
American Medical Association (AMA)
Budaywi, Zaynab Muhsin. Synthesis and characterization of schiff-base ligand derivative from 4-aminoantipyrine and its transition metal complexes. Journal of Kufa for Chemical Science. 2013. Vol. 2013, no. 8, pp.70-78.
https://search.emarefa.net/detail/BIM-372765
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 78
Record ID
BIM-372765
