Synthesis and characterization of imine-azo polymer ligands derive a from azo compounds, acetylacetone and amines and their metal complexes with (Mn+2, Ni+2, Zn+2)
Joint Authors
al-Jamali, Nagham Mahmud
Sabah, Huda
Razzaq, Jihan
Source
Iraqi National Journal of Chemistry
Issue
Vol. 2014, Issue 53 (31 Mar. 2014), pp.76-90, 15 p.
Publisher
University of Babylon College of Sciences
Publication Date
2014-03-31
Country of Publication
Iraq
No. of Pages
15
Main Subjects
Abstract AR
تضمنت الدراسة تحضير بسلسلة مركبات (ليكاندات و بوليمرات) من تفاعل مركب أزو مع ا لأسيتايل أسيئون لينتج مركب ثنائي أيمين-أزو [NAP] و الذي بدوره يتفاعل مع (4-ميثوكسي أنيلين، 2-أمينوثايوفين، 2-أمينوثيازول, 4-امينو بنزامايد) لينتج ليكاندات [BAP, PAP, TAP ,MAP] على التوالي .المركب TAP)) استخدم كليكاند مع أيونات MN2+, Ni2+, Zn2+) لتكوين معقدات و دراسة الظروف المثلى لتعقيدها (تكافؤية المعقدات، النسب المولية، طريقة جوب، الدالة الحامضية، تركيز الليكاند و ألأيونات، التوصيلية المولارية)، مع تحضير بوليمرين.
جميع الليكاندات المحضة مع المعقدات و اليوليمرات درست فعاليتها البكتيرية و الفطرية و كذلك، شخصت بتقنيات (طيف الأشعة تحت الحمراء، طيف بروتون الرنين النووي المغناطيسي، التحليل الدقيق للعناصر) و درجات الانصهار.
Abstract EN
In this work, series of compounds (ligands and polymers) were synthesized from reaction of azo compound with acetylacetone to produce compound diimine azo [NAP], which reacts with (4-aminoethoxy aniline, 2-amino thiophene, 2-amino thiazole, 4-amino benzamide) to produce four ligands [MAP, TAP, PAP, BAP] respectively.
The ligand (TAP) was reacted with (Mn2+,Ni2+,Zn2+)to form metal complexes the optimal conditions of complexes (stoichiometric study, mole ratio, job method, pH, concentration of metals and ligand, molar conductance), were also studied All ligands and complexes and were tested for antibacterial and antifungi activity.
All ligands with complexes were characterized by (1H.NMR–spectra ,FTIR–spectra (CHN)-analysis) , Sehiff base .
American Psychological Association (APA)
al-Jamali, Nagham Mahmud& Sabah, Huda& Razzaq, Jihan. 2014. Synthesis and characterization of imine-azo polymer ligands derive a from azo compounds, acetylacetone and amines and their metal complexes with (Mn+2, Ni+2, Zn+2). Iraqi National Journal of Chemistry،Vol. 2014, no. 53, pp.76-90.
https://search.emarefa.net/detail/BIM-374299
Modern Language Association (MLA)
al-Jamali, Nagham Mahmud…[et al.]. Synthesis and characterization of imine-azo polymer ligands derive a from azo compounds, acetylacetone and amines and their metal complexes with (Mn+2, Ni+2, Zn+2). Iraqi National Journal of Chemistry No. 53 (Mar. 2014), pp.76-90.
https://search.emarefa.net/detail/BIM-374299
American Medical Association (AMA)
al-Jamali, Nagham Mahmud& Sabah, Huda& Razzaq, Jihan. Synthesis and characterization of imine-azo polymer ligands derive a from azo compounds, acetylacetone and amines and their metal complexes with (Mn+2, Ni+2, Zn+2). Iraqi National Journal of Chemistry. 2014. Vol. 2014, no. 53, pp.76-90.
https://search.emarefa.net/detail/BIM-374299
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 90
Record ID
BIM-374299