Synthesis and characterization of some mixed-ligand complexes containing N-acetyl tryptophan and (2, 2′-bipyridine)‎ with some metal salts

Other Title(s)

تحضير وتشخيص بعض المعقدات الفلزية مع ليكاندات مختلطة من_N استيل تربتوفان و 2,2'Bipyridin

Joint Authors

Sarhan, Basimah Muhsin
Hamdan, Taqi al-Din Abd al-Hadi
Nimah, Ban Zaydan

Source

Ibn al-Haitham Journal for Pure and Applied Science

Issue

Vol. 25, Issue 3 (31 Dec. 2012), pp.294-303, 10 p.

Publisher

University of Baghdad College of Education for Pure Science / Ibn al-Haitham

Publication Date

2012-12-31

Country of Publication

Iraq

No. of Pages

10

Main Subjects

Chemistry

Topics

Abstract AR

حضرت و شخصت بعض المعقدات الفلزية التي تحتوي على ليكاندات مختلطة للمشتق N- استيل تربتوفان و 2,2'Bipy, و قد درست هذه المعقدات بالطرائق الطيفية (الأشعة تحت الحمراء, و الأشعة فوق البنفسجية), و التوصيلية المولارية, و الخاصية المغناطيسية و حساب النسبة المئوية للفلز في المعقد.

و من نتائج هذه الدراسات التشخيصية اقترح شكل ثماني السطوح للمعقدات المحضرة كما تم التوصل إلى الصيغة العامة للمعقدات و كما يأتي : [M+n(Acetrp)2(2, 2′-Bipy)]. إذ Hg+2 , Cd+2, Cu+2, Ni+2 , Co+2, Fe+2 , Mn+2=M (Acetrp)- = الليكاند الأيوني (N-acetyl Tryptophan) 2,2′-bipyridine = (2, 2′-Bipy).

Abstract EN

Some metal ions (Mn+2, Fe+2 ,Co+2,Ni+2 ,Cu+2, Cd+2 and Hg+2) complexes of N-acetyl Tryptophan( AcetrpH) and (2, 2′-bipyridine) (2, 2′-Bipy)have been synthesized and then characterized on the basis of their FT-IR, UV-Vis spectroscopy, magneticsuscptibity conductivity measurements and atomic absorption ; from the results obtained and the propsed molecular structure for these complexes as octahedral geometry, the following general formula has been given for the prepared complexes.

[M + n (Acetrp)2 (2, 2′-Bipy)].

Where M = Mn+2, Fe+2 ,Co+2,Ni+2 ,Cu+2, Cd+2 ,Hg+2 (Acetrp)- = Ligand ion(N-acetyl Tryptophan) (2, 2′-Bipy) = 2,2′-bipyridine

American Psychological Association (APA)

Sarhan, Basimah Muhsin& Hamdan, Taqi al-Din Abd al-Hadi& Nimah, Ban Zaydan. 2012. Synthesis and characterization of some mixed-ligand complexes containing N-acetyl tryptophan and (2, 2′-bipyridine) with some metal salts. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 25, no. 3, pp.294-303.
https://search.emarefa.net/detail/BIM-382888

Modern Language Association (MLA)

Sarhan, Basimah Muhsin…[et al.]. Synthesis and characterization of some mixed-ligand complexes containing N-acetyl tryptophan and (2, 2′-bipyridine) with some metal salts. Ibn al-Haitham Journal for Pure and Applied Science Vol. 25, no. 3 (2012), pp.294-303.
https://search.emarefa.net/detail/BIM-382888

American Medical Association (AMA)

Sarhan, Basimah Muhsin& Hamdan, Taqi al-Din Abd al-Hadi& Nimah, Ban Zaydan. Synthesis and characterization of some mixed-ligand complexes containing N-acetyl tryptophan and (2, 2′-bipyridine) with some metal salts. Ibn al-Haitham Journal for Pure and Applied Science. 2012. Vol. 25, no. 3, pp.294-303.
https://search.emarefa.net/detail/BIM-382888

Data Type

Journal Articles

Language

English

Notes

Includes appendices : p. 299-302

Record ID

BIM-382888