Removal of methyl violet dye from synthetic wastewater using a hybrid detoxification process

Other Title(s)

تنقية المياه من صبغة المثيل البنفسجية باستخدام الطريقة الهجينة لإزالة السمية

Joint Authors

Abd al-Rahman, Amir A.
Hamzah, Nur H.
Abd, Muhammad F.

Source

Engineering and Technology Journal

Issue

Vol. 32, Issue 6A (30 Jun. 2014), pp.1544-1561, 18 p.

Publisher

University of Technology

Publication Date

2014-06-30

Country of Publication

Iraq

No. of Pages

18

Main Subjects

Chemistry

Topics

Abstract AR

یھدف البحث إلى دراسة كفاءة مفاعل الطبقة الساقطة في إزالة صبغة المثیل البنفسجیة من المیاه باستخدام ضوء الشمس و ثاني أوكسید التیتانیوم كعامل مساعد.

ثم بحث تأثیر المتغیرات التشغیلیة (تركیز الصبغة, تركیز العامل المساعد, معدل تدفق السائل, حامضیة المحلول, تركیز بیروكسید الھیدروجین) على كفاءة أداء المفاعل في إزالة الصبغة.

بعد إیجاد أفضل الظروف التشغیلیة التي تؤدي إلى أعلى كفاءة للمفاعل و قد وجد أن المفاعل یحقق إزالة بمقدار % 95.27 بعد ساعة من التشغیل و 99.95% بعد ثلاث ساعات من التشغیل.

ثم دراسة حركیة التفاعل للتفاعل الضوئي و وجد أن قانون سرعة التفاعل من الدرجة الأولى بالنسبة لتركیز الصبغة و تطابق مع مودیل Langmuir-Hinshelwood, كما وجدت علاقة تجریبیة تربط بمعدل الإزالة الصبغة مع المتغیرات التشغیلیة.

Abstract EN

The aim of the present study was to design a solar reactor and analyze its performance for removal of methyl violet dye (MV) from water with titanium dioxide as the photo catalyst.

The solar reactor was made up of a flat-plate colorless glass of dimensions 1000 x 750 x 4 mm.

The base of the reactor was made of aluminum.

Various operating parameters were studied to investigate the behavior of the designed reactor like initial dye concentration (CMV = 10-50 mg / L), loading of catalyst (CTiO2 = 200-800 mg / L), suspension flow rate (QL = 0.3-2 L / min), pH of suspension (5-10), and H2O2 concentration (CH2O2 = 200-1000 mg / L).

The operating parameters were optimized to give higher efficiency to the reactor performance.

The designed reactor when operating at optimum conditions offered a degradation of MV up to 95.27 % within one hours of operation time, while a conversion of 99.95 % was obtained in three hours.

The effluent from the photo catalytic reactor was fed to a LPRO separation system which produced a permeat of turbidity value of 0.09NTU.

The product water was analyized using UV spectrophotometer and FTIR.

The analysis results confirmed that the water from the Hybrid-system could be safely recycled and reuse.

It was found that the kinetics of dye degradation was first order with respect to dye concentration and could be well described by Langmuir-Hinshelwood model.

American Psychological Association (APA)

Abd, Muhammad F.& Abd al-Rahman, Amir A.& Hamzah, Nur H.. 2014. Removal of methyl violet dye from synthetic wastewater using a hybrid detoxification process. Engineering and Technology Journal،Vol. 32, no. 6A, pp.1544-1561.
https://search.emarefa.net/detail/BIM-385830

Modern Language Association (MLA)

Abd, Muhammad F.…[et al.]. Removal of methyl violet dye from synthetic wastewater using a hybrid detoxification process. Engineering and Technology Journal Vol. 32, no. 6A (2014), pp.1544-1561.
https://search.emarefa.net/detail/BIM-385830

American Medical Association (AMA)

Abd, Muhammad F.& Abd al-Rahman, Amir A.& Hamzah, Nur H.. Removal of methyl violet dye from synthetic wastewater using a hybrid detoxification process. Engineering and Technology Journal. 2014. Vol. 32, no. 6A, pp.1544-1561.
https://search.emarefa.net/detail/BIM-385830

Data Type

Journal Articles

Language

English

Notes

Includes appendices : p.1554-1561

Record ID

BIM-385830